Results 251 to 260 of about 16,003 (309)

A Crystalline Mono‐Coordinate Indium(I)‐Phosphaalkenyl

open access: yesAngewandte Chemie, EarlyView.
The redox neutral carbometallation of a phospha‐alkyne using the dimeric indium(I) compound (InTer)2 is reported. This reaction affords a mono‐coordinate indium(I) compound that can reversibly extrude the phospha‐alkyne upon addition of a Lewis acid. Abstract The synthesis of the mono‐coordinate indium(I) compound In[C(Ad)═PTer] (Ad = 1‐adamantyl, Ter =
Álvaro García‐Romero   +3 more
wiley   +1 more source

Prediction of chloride ingress and binding in concrete [PDF]

open access: yes, 2006
Geiker, Mette Rica, Nielsen, Erik Pram
core  

Boosting the Nucleophilicity of the Diphenylphosphide Anion with Crown Ether Supported Heavy Alkali Metals to Facilitate Highly Efficient Catalytic Alkene Isomerisation

open access: yesAngewandte Chemie, EarlyView.
Here, we report a breakthrough study in catalytic alkene isomerisation using crown ether‐supported alkali metal phosphides in which the activity increases sequentially and significantly as Group One is descended with Cs(18‐crown‐6)PPh2 (1Cs) performing best.
Felix Krämer   +2 more
wiley   +1 more source

Encapsulated Non‐Exchangeable Na+ Ions Determining the Upper Limit of Al Inclusion in FAU—A Multiscale Simulation

open access: yesAngewandte Chemie, EarlyView.
DFT computation, AIMD simulations, machine learning, statistical analysis, and experimental characterization reveal that the upper limit of Al inclusion in FAU zeolite synthesized under hydrothermal conditions is determined by the encapsulated non‐exchangeable Na+ ions.
Qi Dong   +8 more
wiley   +1 more source

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