Results 51 to 60 of about 11,051 (289)

Polarizable Vanadium Dipoles Promote Water Dissociation on Vanadium‐Based Metal Organic Framework

Advanced Functional Materials, EarlyView.
The polarization of unpaired V 3d electrons weakens the H─O bond to improve water dissociation by the dual Vδ+:O─H and Pλ−:H─O coupling hydrogen bonds formation and relaxation. P@V‐MOF electrocatalyst shows low overpotentials (94 mV in acid, 178 mV in neutral, and 77 mV in alkaline solutions) with excellent stability for effective overall water ...
Xinjuan Liu, Jun Xu, Minmin Fan, Jingcheng Xu, Mengyuan Li, Yun Gong, Weiwei Yang, Lei Li, Yong Zhou, Deqiang Zhao, Yuhua Xue, Xingtao Xu, Chang Q. Sun, Liming Dai   +13 more
wiley   +1 more source

Toward Fast Proton Shuttling in Acidic Oxygen Evolution Reaction

Advanced Functional Materials, EarlyView.
This review establishes proton transfer dynamics as a descriptor governing acidic OER activity, moving beyond the kinetic constraints derived from the proton coupled electron transfer. We discuss how deprotonation governs classical mechanisms, including adsorbate evolution mechanism (AEM), lattice oxygen mechanism (LOM) and oxide path mechanism (OPM ...
Ashish Gaur, Jaeyeong Kim, Sungwook Mhin, HyukSu Han   +3 more
wiley   +1 more source

Recent Advances and Challenges in Anion Exchange Membranes Development/Application for Water Electrolysis: A Review

Membranes
In recent years, anion exchange membranes (AEMs) have aroused widespread interest in hydrogen production via water electrolysis using renewable energy sources.
Lu Liu, Hongyang Ma, Madani Khan, Benjamin S. Hsiao   +3 more
doaj   +1 more source

Coupling Anodic Activity and Stability at Ni‐Based Non‐Oxide Catalysts via Coordinating Alcohol Oxidation and Oxygen Evolution

Advanced Functional Materials, EarlyView.
A cooperative and competitive interrelationship between alcohol oxidation (AOR) and water oxidation (OER) was observed on a typical anode catalyst of Ni2P. In situ Raman spectroscopy and electrochemical analyses revealed a specific complementary mechanism between them, in which OER and AOR critically contribute to the activity and stability of anodic ...
Yong Yan, Xinyu Liu, Yuguo Zhao, Hanwen Jian, Huan Zhou, Riyi Zhang, Dong Wang, Peter Schaaf, Lihua Wang, Guangsheng Guo, Xiayan Wang   +10 more
wiley   +1 more source

Support‐Controlled Reaction Pathways via Dynamic Sulfur‐Mediated Interfaces for Selective Urea Electrolysis

Advanced Functional Materials, EarlyView.
Sulfur‐doped graphitized carbon nanofibers act as adaptive catalyst–support platforms, enabling dynamic sulfur‐mediated reconstruction and strong metal–support interactions. This unique behavior enhances catalyst stability and controls reaction pathways, achieving highly selective urea oxidation (∼92% N2) coupled with efficient hydrogen evolution ...
Melanie Guillén‐Soler, Lucía Vizcaíno‐Anaya, Ahmad Tayyebi, José Manuel Vila‐Fungueiriño, María del Carmen Giménez‐López   +4 more
wiley   +1 more source

Nanocrystalline Fe60Co20Si10B10 as a cathode catalyst for alkaline water electrolysis

, 2022
S.688-697Nanocrystalline Fe60Co20Si10B10, prepared by ball milling atomised powder, was studied as a hydrogen evolution reaction catalyst for alkaline water electrolysis.
Bouzek, K., Rauscher, T., Durovic, M., Bernäcker, C.I., Röntzsch, L., Hnat, J., Paidar, M.   +6 more
core   +1 more source

Nano‐Scale Characterization of Impurities Segregation in Solid Oxide Electrolysis Cells

Advanced Functional Materials, EarlyView.
Cathodic polarization induces impurity segregation in Ni, forming an amorphous Na─Al─Si─O amorphous phase at grain boundaries. Under ultralow oxygen partial pressure, multiple elements dissolve, migrate, and reoxidize within the metal. A patterned model system provides direct nanoscale evidence, clarifying the mechanism of polarization‐driven impurity ...
Zhongtao Ma, Qingjie Wang, Bowen Li, Vasileios Bilalis, Søren Bredmose Simonsen, Ming Chen   +5 more
wiley   +1 more source

Energy Efficiency Improvement of Alkaline Water Electrolysis by using 3D Ni Cathodes Fabricated via a Double-Template Electrochemical Process

Chemical Engineering Transactions, 2013
Alkaline water electrolysis is one of the easiest methods for hydrogen production, offering the advantage of simplicity. Moreover, it represents an environmentally friendly technology for production of high purity hydrogen.
I. Herraiz-Cardona, C. Gonzalez-Buch, E. Ortega, J. Garcia-Anton, V. Perez-Herranz   +4 more
doaj   +1 more source

Sustainable Electrochemical Synthesis of High‐Quality MXenes: Mechanistic Insights, Applications, Challenges, and Technological Prospects

Advanced Functional Materials, EarlyView.
Electrochemical etching provides an eco‐friendly alternative to hazardous HF methods for MXene production. This approach facilitates the selective isolation of the A‐layer from MAX phases with tunable surface terminations. Controlling voltage, electrolytes, temperature, and duration enables the optimal structural integrity. Nevertheless, existing scale
Jagdeep Singh, Madhusudhana M Devadiga, Santosh K. Tiwari, AS Dhaliwal, Gurpreet Singh Selopal   +4 more
wiley   +1 more source

General Synthesis of Amorphous Pd‐Based Nanoparticles Towards Highly Efficient Nitrate‐to‐Ammonia Electrocatalysis

Advanced Functional Materials, EarlyView.
A family of amorphous palladium‐based multi‐component phosphides nanoparticles, synthesized via a robust one‐step wet‐chemical method, overcoming the immiscibility of different elements and the difficulty in forming a stable, disordered structure. When applied in the electrochemical nitrate reduction reaction, these nanocatalysts effectively suppress ...
Lei Xu, Chuhao Luan, Mingzi Sun, Weiwei Chen, Xiaozhi Liu, Chen Ma, Long Zheng, Gang Wang, Peng Han, Ping Gu, Xiao Wang, Chenhao Shu, Cheng Lyu, Zhenyu Zhang, Nailiang Yang, Hongyan He, Xiaohong Li, Dong Su, Bolong Huang, Wenjun Zhang, Ye Chen   +20 more
wiley   +1 more source