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Distinct Catalytic Performance of Cobalt(I)–N-Heterocyclic Carbene Complexes in Promoting the Reaction of Alkene with Diphenylsilane: Selective 2,1-Hydrosilylation, 1,2-Hydrosilylation, and Hydrogenation of Alkene

ACS Catalysis, 2018
Selectivity control on the reaction of alkene with hydrosilane is a challenging task in the development of non-precious-metal-based hydrosilylation catalysts. While the traditional way of selectivity control relies on the use of different ligand type and/
Yafei Gao, Lijun Wang, L. Deng
semanticscholar   +1 more source

Alkenes

1996
This chapter considers the relations between alkanes, alkenes, and alkynes, noting that the first general characteristic of alkenes and alkynes is their tendency to be attacked by electrophiles. It mentions that the spherical s orbital of C may be regarded as near to the positive nucleus, while the pear-shaped p orbital may be considered as farther ...
openaire   +1 more source

Highly Efficient Alkene-Alkene and Arene-Alkene Coupling Reactions with Vicinal Dibromides

Synlett, 1990
Palladium-catalyzed twofold coupling reactions of 1,2-dibromocycloalkenes 4, 7 with alkenes 2 give high yields of (E,Z,E)-1.3,5-hexatrienes 5, 8 which thermally cyclize to ringannulated 1,3-cyclohexadienes 6, 9. Two-, three- and fourfold Heck type coupling reactions were also achieved with vicinal di-13, tri- 16, and tetrabromobenzene 18 under ...
Annegret Lansky   +2 more
openaire   +1 more source

Higher Alkenes

ChemInform, 2005
Bahrmann, H.   +2 more
openaire   +2 more sources

Alkene oligomerization via metallacycles: Recent advances and mechanistic insights

Coordination Chemistry Reviews, 2022
Julien Petit   +2 more
exaly  

A general alkene aminoarylation enabled by N-centred radical reactivity of sulfinamides

Nature Chemistry
Efrey A. Noten   +3 more
semanticscholar   +1 more source

Asymmetric Hydroacylation Involving Alkene Isomerization for the Construction of C3‐Chirogenic Center

Angewandte Chemie - International Edition, 2021
Zhenfeng Zhang   +2 more
exaly  

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