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Molecular structure of the functionalized bismuth alkoxide Bi[OC(CH2 NMe2)3]3 [PDF]

Main Group Metal Chemistry, 2014
The molecular structure of the amino-functionalized bismuth alkoxide, Bi[OC(CH2 NMe2)3]3 has been determined and embodies a six-coordinate bismuth atom with a fac, fac-BiO3 N3 coordination sphere.
Kociok-Köhn Gabriele, Molloy Kieran C., Palmer Liam   +2 more
doaj   +2 more sources

Heterobimetallic Uranium(V)-Alkali Metal Alkoxides: Expanding the Chemistry of f-Block Elements [PDF]

Molecules
Heterobimetallic uranium(V) alkoxides incorporating monovalent alkali metal counterions display remarkable structural versatility, dictated by the steric demands of the alkoxide ligands and the ionic radius of the alkali metal.
Andreas Lichtenberg, Lidia Inderdühnen, Aida Lichtenberg, Sanjay Mathur   +3 more
doaj   +2 more sources

Transparent and high-porosity aluminum alkoxide network-forming glasses [PDF]

Nature Communications
Metal-organic network-forming glasses are an emerging type of material capable of combining the modular design and high porosity of metal-organic frameworks and the high processability and optical transparency of glasses.
Zihui Zhang, Yingbo Zhao
doaj   +2 more sources

An unusual chiral-at-metal mechanism for BINOL-metal asymmetric catalysis [PDF]

Nature Communications
Chiral binaphthols (BINOL)-metal combinations serve as powerful catalysts in asymmetric synthesis. Their chiral induction mode, however, typically relies on multifarious non-covalent interactions between the substrate and the BINOL ligand.
Zhenxing Li, Pengfei Chen, Zhigang Ni, Liuzhou Gao, Yue Zhao, Ranran Wang, Congqing Zhu, Guoqiang Wang, Shuhua Li   +8 more
doaj   +2 more sources

Simple Methylcadmium Alkoxides [PDF]

Zeitschrift für Naturforschung B, 2007
The reaction of dimethylcadmium with alcohols R-OH in equimolar ratio leads to the formation of tetrameric methylcadmium alkoxides with molecular formula [(MeCd)4 (OR)4] [R = Me (1), Et (2) and iPr (3)]. These compounds have been characterised by 1H, 13C NMR and IR spectroscopy, by mass spectrometry, elemental analyses and by X-ray crystallography (for
Jana, Surajit, Pape, Tania, Mitzel, Norbert W.   +2 more
openaire   +1 more source

Proton-Coupled Electron Transfer at the Surface of Polyoxovanadate-Alkoxide Clusters

Accounts of Chemical Research, 2023
Conspectus Proton-coupled electron transfer (PCET) is a fundamental process involved in all areas of chemistry, with relevance to biological transformations, catalysis, and emergent energy storage and conversion technologies.
Kathryn R Proe, Eric Schreiber, E. Matson   +2 more
semanticscholar   +1 more source

Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route [PDF]

Journal of the Serbian Chemical Society, 2006
Titanium anodes with an active RuO2 coating of two different thicknesses were prepared from the oxide suspended in ethanol ("ink" method), while the oxide itself was synthesized by the hydrolysis of ruthenium ethoxide in an ethanolic solution (alkoxide ...
Panić Vladimir, Dekanski Aleksandar, Milonjić Slobodan, Mišković-Stanković Vesna B., Nikolić Branislav   +4 more
doaj   +3 more sources

Mononuclear Dysprosium Alkoxide and Aryloxide Single‐Molecule Magnets

Chemistry, 2021
Recent studies have shown that mononuclear lanthanide (Ln) complexes can be high‐performing single‐molecule magnets (SMMs). Recently, there has been an influx of mononuclear Ln alkoxide and aryloxide SMMs, which have provided the necessary geometrical ...
V. S. Parmar, D. P. Mills, R. Winpenny
semanticscholar   +1 more source

Grafting of L-proline and L-phenylalanine amino acids on kaolinite through synthesis catalyzed by boric acid

Applied Surface Science Advances, 2021
The amidation reaction catalyzed by boric acid between the amino acids proline and phenylalanine and the alkoxide 3-aminopropyltriethoxysilane was studied. Afterwards, the modified alkoxide was used to functionalize the clay mineral kaolinite. The hybrid
Denis T. de Araújo, Katia J. Ciuffi, Eduardo J. Nassar, Miguel A. Vicente, Raquel Trujillano, Vicente Rives, Elena P. Bernal, Emerson H. de Faria   +7 more
doaj   +1 more source

Tin dioxide sol-gel derived thin films deposited on porous silicon [PDF]

, 1996
Undoped and Sb-doped SnO2 sol¿gel derived thin films have been prepared for the first time from tin (IV) ethoxide precursor and SbCl3 in order to be utilised for gas sensing applications where porous silicon is used as a substrate.
Berg, A. van den, Buiu, O., Cobianu, C., Dascula, D., Parlog, C., Pecz, B., Savaniu, C., Varsony, E., Zaharescu, M.   +8 more
core   +15 more sources