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Halogen-containing tetrametallic aluminium alkoxides
Dalton Transactions, 2008New halogen-containing tetrametallic aluminium alkoxides of formula [Al{(mu-OEt)2AlMeCl}3] ( 2-cis; 2-trans), and [Al{(mu-OEt)2AlBr2}3] ( 4), have been synthesized by combining Al(OEt)3 and Me2AlCl (for 2) or EtAlBr2 (for 4). They were fully characterized by (1H, 27Al) NMR, IR, mp, elemental analysis, and single-crystal X-ray diffractometry.
Amitabha, Mitra +3 more
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Polyoxovanadate-Alkoxide Clusters as a Redox Reservoir for Iron.
Inorganic Chemistry, 2017Feng Li +13 more
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Organometallic oxides, alkoxides, and peroxides. Part III. Phenylmercury(II) alkoxides
Journal of the Chemical Society C: Organic, 1970Phenylmercury(II) alkoxides have been prepared in high yields by the reaction of phenylmercury(II) oxide or hydroxide with dialkyl carbonates, and by the reaction of phenylmercury(II) methoxide with higher boiling alcohols. Molecular weights indicate that in boiling benzene these compounds are associated, and that the degree of association decreases ...
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1983
Publisher Summary This chapter discusses the transition-metal alkoxides. Primary alkoxides of chromium (III) do not appear to undergo alcoholysis reactions, even under forcing conditions with other alcohols. This is rather unusual in view of the usually strong lability of the alkoxy groups exhibited in alkoxides of most of the metals studied; the ...
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Publisher Summary This chapter discusses the transition-metal alkoxides. Primary alkoxides of chromium (III) do not appear to undergo alcoholysis reactions, even under forcing conditions with other alcohols. This is rather unusual in view of the usually strong lability of the alkoxy groups exhibited in alkoxides of most of the metals studied; the ...
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Hydroxy-Directed Amidation of Carboxylic Acid Esters Using a Tantalum Alkoxide Catalyst.
Journal of the American Chemical Society, 2016H. Tsuji, Hisashi Yamamoto
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Self-Assembled, Iron-Functionalized Polyoxovanadate Alkoxide Clusters.
Inorganic Chemistry, 2016Feng Li +3 more
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