Results 41 to 50 of about 55,562 (339)

Synthesis and characterization of mesoporous TiC nanopowder/nanowhisker with low residual carbon processed by sol–gel method

open access: yesJournal of Materials Research and Technology, 2023
In the present research, Titanium carbide nanopowders and nanowhiskers were synthesized by the sol-gel process using phenolic resin and titanium alkoxide as precursors.
Fahimeh Sharifi   +4 more
doaj   +1 more source

Aluminosilicates compacts by alkoxide route: influence of Ba addition

open access: yesCerâmica, 1999
The sol-gel route was employed to obtain three different powders with the stoichiometric composition corresponding to mullite (3 Al2O3.2SiO2): (i) commercial alumina and silica from sol-gel, (ii) alumina and silica by alkoxide partial hydrolysis, (iii ...
N. E. Quaranta, E. R. Benavidez
doaj   +1 more source

Precursor type affecting surface properties and catalytic activity of sulfated zirconia [PDF]

open access: yesActa Periodica Technologica, 2007
Zirconium-hydroxide precursor samples are synthesized from Zr-hydroxide, Zr-nitrate, and Zr-alkoxide, by precipitation/impregnation, as well as by a modified sol-gel method. Precursor samples are further sulphated for the intended SO4 2- content of 4 wt.%
Zarubica Aleksandra R.   +1 more
doaj   +1 more source

Potentialities of the sol-gel route to develop cathode and electrolyte thick layers Application to SOFC systems [PDF]

open access: yes, 2008
In this work, we report the potential of sol–gel process to prepare cathode and electrolyte thin and thick layers on anodic NiO-YSZ supports which were also made from powders prepared by sol–gel route.
Ansart, Florence   +5 more
core   +4 more sources

Archeo‐Inspiration from the Cultural History of Glass: Historic Accounts, Anecdotes and Hard Facts as Challenges to Modern Material Science

open access: yesAdvanced Materials, EarlyView.
Glass, historically valued for its purity and durability, has long inspired artists and societies. This article introduces the concept of “Archeo‐Inspiration”, drawing on cultural and historical contexts of glass to guide future material innovations.
Eva von Contzen   +3 more
wiley   +1 more source

Biocatalytic Regioselective C‐Formylation of Resorcinol Derivatives

open access: yesAngewandte Chemie, EarlyView.
An acyltransferase from Chromobacterium sphagni (CsATase) was identified that catalyzes the regioselective formylation of resorcinol substrates. The formylation of substituted resorcinol derivatives yielded mono‐formylated products with up to 99% conversion and up to 74% isolated yield.
Lilla Gal   +6 more
wiley   +2 more sources

Molecular structure of dimeric ethoxytin trichloride ethanol solvate

open access: yesMain Group Metal Chemistry, 2013
The title compound Sn2Cl6(OEt)2(HOEt)2, accidentally obtained as a side product from the reaction of 2,6-Mes2C6H3Li with SnCl4 in Et2O, was investigated by single crystal X-ray diffraction.
Beckmann Jens   +2 more
doaj   +1 more source

Unexpected C–O Bond Cleavage by a Copper–Phosphido Compound

open access: yesMolbank, 2023
Copper methoxide compound IPrCuOMe was unexpectedly formed in a reaction of IPrCuPPh2 with methyl acrylate. The alkoxide product was identified from the reaction mixture spectroscopically and structurally characterized.
Steven G. Dannenberg, Rory Waterman
doaj   +1 more source

Use of metal catalysts bearing Schiff base macrocycles for the ring opening polymerization (ROP) of cyclic esters [PDF]

open access: yes, 2017
© 2017 by the authors. Schiff base macrocycles are emerging as useful scaffolds for binding two or more catalytic metals in close proximity. Such coordination chemistry allows for the evaluation of potentially beneficial catalytic cooperative effects. In
Redshaw, Carl
core   +2 more sources

Crystal Structure of the Isopropylzinc Alkoxide of Pyrimidyl Alkanol: Mechanistic Insights for Asymmetric Autocatalysis with Amplification of Enantiomeric Excess

open access: yesAngewandte Chemie, 2015
Asymmetric amplification during self-replication is a key feature that is used to explain the origin of homochirality. Asymmetric autocatalysis of pyrimidyl alkanol in the asymmetric addition of diisopropylzinc to pyrimidine-5-carbaldehyde is a unique ...
A. Matsumoto   +6 more
semanticscholar   +1 more source

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