Results 51 to 60 of about 55,562 (339)

Low Resistance Interphase Formation at the PEO‐LiTFSI|LGPS Interface in Lithium Solid‐State Batteries

Advanced Materials Interfaces, EarlyView.
Interfacial charge transfer and low‐resistance interphase formation between PEO‐based polymer and Li10GeP2S12 solid electrolytes are investigated using multi‐electrode impedance spectroscopy and advanced analytical techniques such as XPS and ToF‐SIMS.
Ujjawal Sigar, Timo Weintraut, Sebastian L. Benz, Semih Engün, Sascha Kremer, Anja Henss, Felix H. Richter   +6 more
wiley   +1 more source

Boosting the Nucleophilicity of the Diphenylphosphide Anion with Crown Ether Supported Heavy Alkali Metals to Facilitate Highly Efficient Catalytic Alkene Isomerisation

Angewandte Chemie, EarlyView.
Here, we report a breakthrough study in catalytic alkene isomerisation using crown ether‐supported alkali metal phosphides in which the activity increases sequentially and significantly as Group One is descended with Cs(18‐crown‐6)PPh2 (1Cs) performing best.
Felix Krämer, Thomas M. Horsley Downie, Robert E. Mulvey   +2 more
wiley   +2 more sources

Crystal structure and computational analysis of tetrakis(acetonitrile)bis(nonafluoro-tert-butanolato)titanium(III) complex as a salt of the weakly coordinating [Al{OC(CF3)3}4]− anion

Acta Crystallographica Section E: Crystallographic Communications
The title compound, [Ti(C4F9O)2(C2H3N)4][Al(C4F9O)4] or [Ti{OC(CF3)3}2(CH3CN)4][Al{OC(CF3)3}4], is the first structurally characterized complex of TiIII containing four acetonitrile molecules and perfluorinated alkoxyaluminate in its coordination sphere.
Przemysław Jan Malinowski, Kacper Koteras   +1 more
doaj   +1 more source

Surprisingly facile CO2 insertion into cobalt alkoxide bonds: A theoretical investigation

Beilstein Journal of Organic Chemistry, 2015
Exploiting carbon dioxide as co-monomer with epoxides in the production of polycarbonates is economically highly attractive. More effective catalysts for this reaction are intensively being sought.
Willem K. Offermans, Claudia Bizzarri, Walter Leitner, Thomas E. Müller   +3 more
doaj   +1 more source

Application of Organosilicon Modifier Based on Tetraethoxysilane for the Production of Heat-Resistant Chrysotile Fibers and Reinforced Cement Composites

Fibers, 2023
This research is aimed at obtaining boron-containing nanotubular chrysotile fibers with increased neutron absorption capacity. The possibility of using an organosilicon modifier based on tetraethoxysilane to increase the hydrothermal stability of ...
Roman Nikolaevich Yastrebinsky, Vyacheslav Ivanovich Pavlenko, Anna Viktorovna Yastrebinskaya, Andrey Ivanovich Gorodov, Anastasia Vladislavovna Akimenko   +4 more
doaj   +1 more source

Modification of chiral dimethyl tartrate through transesterification : immobilisation on POSS and enantioselectivity reversion in Sharpless asymmetric epoxidation [PDF]

, 2010
Modification of dimethyl tartrate has been investigated through transesterification with aminoalcohols to provide reactive functionalities for the covalent bonding of chiral tartrate to polyhedral oligomeric silsesquioxanes.
García, Rafael A., Gibson, Colin L., Iglesias, José, Sherrington, David C., Van Grieken, Rafael   +4 more
core   +1 more source

Room Temperature Synthesis and Photopatterning of Mesoporous Titanium Dioxide Thin Films

Advanced Materials Technologies, EarlyView.
A nanofabrication strategy combining deep‐UV photolithography with block copolymer self‐assembly enables direct patterning and mineralization of mesoporous TiO2 thin films at room temperature. Photocatalytic titanium oxo‐clusters promote polymer degradation under UV irradiation, enabling multiscale control over porosity, film thickness, and lateral ...
Youssef Ghossoub, Laurent Noel, Dominique Berling, Victor Malgras, David Grosso, Olivier Soppera   +5 more
wiley   +1 more source

Powder preparation and compaction behaviour of fine-grained Y-TZP [PDF]

, 1990
Two wet chemical preparation methods are described for yttria-doped tetragonal zirconia powders. Both methods yield powders with an extremely small crystallite size (8 nm) and a narrow size distribution.
Burggraaf, A.J., Groot Zevert, W.F.M., Theunissen, G.S.A.M., Winnubst, A.J.A.   +3 more
core   +3 more sources

Programmable Dimensional Lithography with Digital Micromirror Devices for Multifunctional Microarchitectures

Advanced Materials Technologies, EarlyView.
This review explores recent advances in digital micromirror device (DMD)‐based lithography, focusing on its programmable light modulation, multi‐material compatibility, and dimensional patterning strategies. It highlights innovations from optical system design to materials integration and multifunctional applications, positioning DMD lithography as a ...
Yubin Lee, Byungcheon Yoo, Chaeyeong Ryu, Jongwon Oh, Dahye Baek, Jiseok Lee   +5 more
wiley   +1 more source

Synthesis and textural properties of unsupported and supported rutile (TiO2) membranes [PDF]

, 1993
Two approaches were postulated for improving the stability of porous texture of titania membranes: (1) retarding the phase transformation and grain growth; (2) avoiding the phase transformation.
Burggraaf, Anthonie J., Keizer, Klaas, Kumar, Krishnankutty-Nair P., Nagamoto, Hidetoshi, Okubo, Tatsuya   +4 more
core   +3 more sources