Results 241 to 250 of about 121,575 (333)

A Crystalline Mono‐Coordinate Indium(I)‐Phosphaalkenyl

Angewandte Chemie, EarlyView.
The redox neutral carbometallation of a phospha‐alkyne using the dimeric indium(I) compound (InTer)2 is reported. This reaction affords a mono‐coordinate indium(I) compound that can reversibly extrude the phospha‐alkyne upon addition of a Lewis acid. Abstract The synthesis of the mono‐coordinate indium(I) compound In[C(Ad)═PTer] (Ad = 1‐adamantyl, Ter =
Álvaro García‐Romero, Maren Pink, Israel Fernández, Jose M. Goicoechea   +3 more
wiley   +1 more source

Intermolecular Synthesis of Coumarins from Acid Chlorides and Unactivated Alkynes through Palladium Catalysis. [PDF]

Org Lett
Schmitt HL, Staeck N, Müller P, Bogdos MK, Morandi B.   +4 more
europepmc   +1 more source

Boosting the Nucleophilicity of the Diphenylphosphide Anion with Crown Ether Supported Heavy Alkali Metals to Facilitate Highly Efficient Catalytic Alkene Isomerisation

Angewandte Chemie, EarlyView.
Here, we report a breakthrough study in catalytic alkene isomerisation using crown ether‐supported alkali metal phosphides in which the activity increases sequentially and significantly as Group One is descended with Cs(18‐crown‐6)PPh2 (1Cs) performing best.
Felix Krämer, Thomas M. Horsley Downie, Robert E. Mulvey   +2 more
wiley   +1 more source

Boraindenes as versatile precursors to benzannulated boron heterocycles. [PDF]

Chem Sci
Wieprecht N, Krummenacher I, Wüst L, Michel M, Neder M, Häfner A, Karg J, Braunschweig H.   +7 more
europepmc   +1 more source

Ethane Chlorination Toward Vinyl Chloride Synthesis: Mechanistic and Catalytic Perspectives

Angewandte Chemie, EarlyView.
Ethane chlorination is emerging as a promising low‐carbon route to vinyl chloride monomer, yet it remains academically underexplored due to the complexity of radical chemistry. As the first focused Minireview on this topic, it offers forward‐looking mechanistic analysis, unveils catalyst evolution pathways, and defines research priorities to accelerate
Xia Wu, Guodong Huo, Haifeng Qi, Qinggang Liu, Nicholas F. Dummer, Graham J. Hutchings, Yanqiang Huang   +6 more
wiley   +1 more source

Catalytic Asymmetric 1,2-Migration/Allylation of Alkynyl Boronate Complexes: A Modular Route to Enantioenriched Skipped 1,4-Dienes. [PDF]

J Am Chem Soc
Wei L, Guo Z, Tyler JL, Aggarwal VK.
europepmc   +1 more source

Programmable Nanoscale Motion via Molecular Patterning on DNA Origami

Angewandte Chemie, EarlyView.
DNA origami nanorods enable precise urease placement with tunable coverage and asymmetry, revealing that propulsion depends on a balance of catalytic loading and geometry. Maximum speed occurs at ∼25% end‐coverage and declines as enzyme distribution becomes more symmetrical.
Lars Paffen, Maurik Engelbert van Bevervoorde, Andoni Rodriguez‐Abetxuko, Loai Abdelmohsen, Remco van der Hofstad, Jan C.M. van Hest, Tania Patiño Padial   +6 more
wiley   +1 more source

Iron-Catalyzed trans-Hydrostannation of Terminal Alkynes. [PDF]

Angew Chem Int Ed Engl
Chakrabortty S, Fürstner A.
europepmc   +1 more source

3-Component reactions for accessing heterocycle-rich topologies: trapping of pyrrole-stabilized carbenes <i>via</i> net bimolecular C-H or N-H insertion. [PDF]

Chem Sci
Guzman AL, Toll KB, Hoye TR.
europepmc   +1 more source