Results 121 to 130 of about 11,640 (313)

Superionic Amorphous Li2ZrCl6 and Li2HfCl6

open access: yesAdvanced Materials, EarlyView.
Amorphous Li2HfCl6 and L2ZrCl6 are shown to be promising solid‐state electrolytes with predicted ionic conductivities >20 mS·cm−1. Molecular dynamics simulations with machine‐learning force fields reveal that anion vibrations and flexible MCl6 octahedra soften the Li coordination cage and enhance mobility. Correlation between Li‐ion diffusivity and the
Shukai Yao, De‐en Jiang
wiley   +1 more source

Solid state electrolytes for all-solid-state 3D lithium-ion batteries

open access: yes, 2012
The focus of this Ph.D. thesis is to understand the lithium ion motion and to enhance the Li-ionic conductivities in commonly known solid state lithium ion conductors by changing the structural properties and preparation methods. In addition, the feasibility for practical utilization of several studied solid electrolyte materials in 3D all-solid-state ...
openaire   +2 more sources

Chemomechanical Origin of Morphological Disparity in Lithium Metal Electrodeposition

open access: yesAdvanced Materials, EarlyView.
Selective dissociation of either solvent or salt on copper current collector induced different solid electrolyte interphase (SEI) layers. The solvent derived organic SEI favors formation of Li whisker, while salt derived SEI favors formation of Li particle, revealing the root cause of Li morphology disparity within the same cell.
Yaobin Xu   +8 more
wiley   +1 more source

Decoding High‐voltage LiCoO2: From Degradation to Stabilization Toward Durable Li‐ion Batteries

open access: yesAdvanced Materials, EarlyView.
This review systematically addresses the degradation mechanisms and stabilization strategies for high‐voltage LiCoO2 cathodes. Key enhancement approaches including foreign‐ion doping, surface modifications, structural design, and electrolyte optimization are critically assessed.
Zezhou Lin   +6 more
wiley   +1 more source

Redefining Separator Design and Water Activity for High‐Energy Zinc Batteries Using Covalent Organic Framework

open access: yesAdvanced Materials, EarlyView.
Device‐level zinc batteries are energy‐limited by the mass/volume of inactive components, while lean‐electrolyte operation triggers interfacial water depletion and unstable kinetics. Here we elucidate lean‐failure mechanisms and develop a COF@PAN functional separator that regulates hydrogen‐bonding networks to manage water activity and accelerate ...
Kun Zhang   +12 more
wiley   +1 more source

Self‐Regulating Sodium‐Ion Battery Materials: From Phase Reconstruction to Functional Activation

open access: yesAdvanced Materials, EarlyView.
Self‐regulating sodium‐ion batteries hinge on programmable phase behavior in layered oxides, interphases that renew without growth, and electrolytes that steer solvation and chemistry. This review distills mechanisms into design rules that span composition, site and entropy tuning, and self‐buffering anodes, linking operando evidence to choices and ...
Hong Gao   +10 more
wiley   +1 more source

Preparation of Lithium Ion Conductor Glass-Ceramic with High Conductivity for Producing Lithium-Air and all-Solid-State Lithium-Ion Batteries

open access: yesJournal of Advanced Materials in Engineering, 2017
In this research, new lithium ion conductor glass-ceramics with NASICON-type structure (Li1+x+yAlxCryGe2-x-y (PO4)3, x+y=0.5) were synthesized using melt-quenching method and converted to glass-ceramics through heat treatment.
M. Illbeigi   +3 more
doaj   +2 more sources

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