Making Blank Faces Expressive: Chemical Approaches to the Modification of Chemically Inert Peptides
As an alternative to the conventional approach, which combines amino acid monomers in a one‐by‐one fashion to peptide derivatives, the chemical modification of existing peptides has attracted significant attention in recent years. However, such approaches generally target the reactive functional groups in cysteine and lysine residues, particularly in ...
Yoshitaka Moriyama +2 more
wiley +1 more source
Difluorinative Cyclopropene Rearrangement by I(I)/I(III) Catalysis: Regio- and Stereoselective Synthesis of Allyl Difluorides. [PDF]
Wang ZX +3 more
europepmc +1 more source
Halogen bonding-induced 1,3-carbohydroxylation of allyl carboxylates <i>via</i> 1,2-cationic acyloxy migration (1,2-CAM). [PDF]
Sharma S +5 more
europepmc +1 more source
The synergistic interplay of electricity, light and earth‐abundant, nontoxic iron catalysis allowed for the efficient recycling of post‐consumer polymers into value‐added products. This robust depolymerization strategy was viable on multigram‐scale, where the cathodic hydrogen evolution reaction presents an attractive opportunity for a green hydrogen ...
Maxime Hourtoule +5 more
wiley +1 more source
Allyl nonanoate as a novel bile-derived biomarker in metabolic dysfunction-associated steatotic liver disease. [PDF]
Lee SH +7 more
europepmc +1 more source
Alkynyltriazenes in Photochemical Metal‐Free Doyle–Kirmse Rearrangements
A metal‐ and additive‐free photocatalytic Doyle–Kirmse reaction of alkynyl triazenes is described, proceeding via cyanocarbene intermediates. This strategy enables the efficient construction of highly substituted asymmetric carbon centers with broad substrate scope, delivering synthetically valuable nitriles.
Ningning Liu +7 more
wiley +1 more source
Catalytic Enantioselective Cross-Nucleophile Coupling via Valence Tautomerism. [PDF]
Zhang Z +8 more
europepmc +1 more source
Polysiloxane Networks Modified by Nitrogen-Containing Organic Compounds. [PDF]
Chechelska-Noworyta A +2 more
europepmc +1 more source
Photocatalytic synthesis of homoallylic amines <i>via</i> nucleophilic addition of nickel allyl complexes to imines. [PDF]
Nopper C +5 more
europepmc +1 more source
Ring Formation in Sesquiterpene Synthesis: Biomimetic vs. Non‐Biomimetic Strategies
A short review of cyclase enzyme‐mediated ring formation in sesquiterpene biosynthesis is presented as a prelude to six case studies examining the merits and demerits of biomimetic vs. non‐biomimetic strategies for carbocyclisation in the total synthesis of this iconic natural product class.
Bohan Lin, Chen Dai, Alan C. Spivey
wiley +1 more source

