Results 161 to 170 of about 39,991 (242)

CO2 Capture with Liquid-Liquid Phase Change Solvents: A Thermodynamic Study [PDF]

open access: yes, 2017
Arshad   +22 more
core   +1 more source

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

open access: yesChemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

l‐Leucine‐Based Layered Coordination Polymer Supports for Immobilizing Basic Salts to Yield Solid CO2 Adsorbents Resistant to Moisture and Oxidation

open access: yesChemistry – A European Journal, EarlyView.
A layered amino acid–based coordination polymer, (Zn(Leu)2), acts as a support that immobilizes diverse basic salts. The resulting solid sorbents remain nondeliquescent under humid, DAC‐relevant feeds while enabling CO2 capture. The interlayer‐immobilized sorbents exhibit high oxidative stability after accelerated oxidative aging, unlike conventional ...
Yuki Kohno, Takuji Ikeda, Takashi Makino
wiley   +1 more source

Catalytic Amyloids: Turning Fibrils Into Biocatalysts

open access: yesChemistry – A European Journal, EarlyView.
Amyloids, traditionally associated with diseases, have emerged as versatile catalytic scaffolds. From natural amyloid sequences to bioinspired and de novo designs, we highlight strategies to construct catalytic active sites and anchor enzymes onto fibrils, creating versatile nanomaterials with tunable activities. ABSTRACT Amyloids have been regarded as
Alessandra Esposito   +3 more
wiley   +1 more source

Two‐Step Synthesis of a Chiral Fluorinated Alcohol With Silica‐Supported Enzyme RrADH in Batch and Continuous Flow Mode

open access: yesChemistry – A European Journal, EarlyView.
A two‐step process was transferred from batch to flow mode for the synthesis of (R)‐2‐fluoro‐1‐phenylethanol as a benchmark, consisting of a decarboxylative fluorination in aqueous media, followed by an enantioselective biocatalytic reduction of the prochiral intermediate with RrADH immobilized on silica supraparticles.
Egzon Cermjani   +7 more
wiley   +1 more source

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