Results 171 to 180 of about 47,582 (230)

Diacetylene‐Functionalized Glycan Mimetics for Receptor‐Mediated Cluster Imprinting in Model Membranes

open access: yesMacromolecular Rapid Communications, EarlyView.
Diacetylene‐containing glycan mimetics cluster upon selective lectin binding in GUVs. Subsequent irradiation leads to the formation of fluorescent polymer clusters, while non‐clustered glycan mimetics remain unaffected in the membrane. ABSTRACT The glycocalyx, a dense layer of glycoproteins and glycolipids on eukaryotic cells, is essential for cellular
Luca‐Cesare Blawitzki   +5 more
wiley   +1 more source

Latex Serum‐Derived Supramolecular Networks Enable Toughening of Natural Rubber

open access: yesMacromolecular Rapid Communications, EarlyView.
Latex‐serum addition enhances strain‐induced crystallization (SIC) toughening in natural rubber, increasing tearing strength and extending the SIC activation window. Supramolecular networks form via bifurcated hydrogen bonding between polyol components (e.g., quebrachitol) and end‐functionalized polyisoprene chains, serving as effective crystallization
Katsuhiko Tsunoda   +5 more
wiley   +1 more source

Catechol‐Containing Poly(2‐isopropyl‐2‐oxazoline): Synthesis and Thermoresponsive Behavior in Aqueous Salt Solutions

open access: yesMacromolecular Rapid Communications, EarlyView.
Polymers carrying catechol groups are interesting mussel‐inspired materials for wet adhesion applications or metal ion complexation for wastewater treatment. Here, catechol‐containing poly(2‐isopropyl‐2‐oxazoline)s were synthesized via microwave‐assisted cationic (co)polymerization and examined with regard to their thermoresponsive LCST behavior in ...
Niclas Madaj   +4 more
wiley   +1 more source

Multiple‐Use Microplate Assay for Submicromolar Ultra High‐Throughput Separation of Amines Based on their Degree of Substitution

open access: yesChemistryOpen, EarlyView.
A reusable microplate platform for ultra‐high‐throughput, submicromolar separation of protonated amines – including alkyl‐, aryl‐, and aralkyl‐types – using a tris(pyridino)‐crown ether selector was introduced; the method enables rapid, zero‐energy, parallel purification fully compatible with automated synthesis workflows.
Panna Vezse   +3 more
wiley   +1 more source

2,3‐Dichloro‐5,6‐Dicyano‐1,4‐Benzoquinone (DDQ)‐Mediated CC Bond Formation: Redox Strategies from Stoichiometric to Catalytic Systems

open access: yesChemistryOpen, EarlyView.
2,3‐Dichloro‐5,6‐dicyano‐1,4‐benzoquinone serves as a versatile oxidant and redox catalyst for CC bond formation through hydride abstraction or single‐electron transfer. Stoichiometric and catalytic systems enable benzylic, allylic, and aromatic CH activation under mild, metal‐free conditions, providing sustainable routes to complex and bioactive ...
Dohoon Cha, Sun‐Joon Min
wiley   +1 more source

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