Transformation of struvite from wastewater to a hydrogen fuel storage compound ammonia borane [PDF]
Frontiers in Chemistry, 2023 Ammonia borane (NH3BH3) is a carrier of hydrogen gas that is known as a carbon-free renewable energy source. A high hydrogen content of ammonia borane and its stability in air at ambient temperatures make it a valuable molecule for its potential use as a
Nin Dingra +4 more
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Ammonia–Borane-Mediated Reduction of Nitroalkenes [PDF]
SynOpen, 2020 Ammonia borane (AB) has been successfully employed in the reduction of nitroalkenes. A variety of nitrostyrenes and alkyl-substituted nitroalkenes were chemoselectively reduced to the corresponding nitroalkanes, in short reaction time, with an atom ...
Chiara Faverio +3 more
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Room Temperature Reduction of Titanium Tetrachloride-Activated Nitriles to Primary Amines with Ammonia-Borane [PDF]
Molecules, 2022 The reduction of a variety of aromatic and aliphatic nitriles, activated by a molar equivalent of titanium tetrachloride, has been achieved at room temperature using ammonia borane as a safe reductant. The corresponding methanamines were isolated in good
P. Veeraraghavan Ramachandran +1 more
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Chemical Engineering Transactions, 2020 As a material with high hydrogen storage density, ammonia borane has attracted the attention of researchers. Ammonia borane can release hydrogen gas through hydrolytic dehydrogenation and pyrolysis dehydrogenation, where hydrolytic dehydrogenation has a ...
Suitao Qi +3 more
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Tuning the Solid-State Hydrogen Release of Ammonia Borane by Entrapping the Intermediates: The Role of High-Boiling-Point Amines [PDF]
MoleculesAmmonia borane is a promising hydrogen storage material due to its high hydrogen content, but its use as hydrogen carrier under thermal stimuli involves the production of several byproducts, such as borazine, reducing hydrogen purity and the overall ...
Mattia Bartoli +5 more
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Spontaneous formation of boron nitride nanotube fibers by boron impurity reduction in laser ablation of ammonia borane [PDF]
Nano Convergence, 2022 Highly crystalline and few-walled boron nitride nanotubes (BNNTs) had been synthesized by laser ablation using only ammonia borane as a precursor. As a molecular precursor, ammonia borane supplied both B and N atoms with a ratio of 1:1, and BNNTs were ...
Dong Su Bae +7 more
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Efficient Organocatalytic Dehydrogenation of Ammonia Borane. [PDF]
Angew Chem Int Ed Engl, 2020 AbstractDehydrogenation of ammonia borane by sterically encumbered pyridones as organocatalysts is reported. With 6‐tert‐butyl‐2‐thiopyridone as the catalyst, a turnover frequency (TOF) of 88 h−1 was achieved. Experimental mechanistic investigations, substantiated by DLPNO‐CCSD(T) computations, indicate a mechanistic scenario that commences with the ...
Hasenbeck M, Becker J, Gellrich U.
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Thermal Interaction Mechanisms of Ammonium Perchlorate and Ammonia Borane [PDF]
MoleculesAmmonia borane (AB), with a theoretical hydrogen content of 19.6 wt%, is constrained by its low crystalline density (0.758 g/cm3) and poor thermal stability (decomposing at 100 °C).
Yunlong Zhang +3 more
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A pH-sensitive liposomal co-delivery of fingolimod and ammonia borane for treatment of intracerebral hemorrhage [PDF]
Nanophotonics, 2022 Intracerebral hemorrhage (ICH) is one of the most devastating types of stroke. This study aims to develop a new drug carrier with hematoma-specific response and high property. pH-sensitive liposomes (PSL) were developed.
Gong Xiyu +5 more
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Ammonia Borane All-In-One Modification Strategy Enables High-Performance Perovskite Solar Cells [PDF]
Nano-Micro LettersHighlights An all-in-one modification strategy was developed by introducing a multifunctional complex ammonia borane (BNH6) into the buried and upper interfaces simultaneously.
Jiaxin Ma +8 more
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