Results 31 to 40 of about 9,481 (204)

Ammonia borane-based nanocomposites as solid state hydrogen stores for portable power applications [PDF]

open access: yes, 2018
Ammonia borane (AB) based nanocomposites have been investigated with the aim of developing a promising solid-state hydrogen store that complies with the requirements of a modular polymer electrolyte membrane fuel cell (PEM FC) in a portable power pack ...
Bielewski, Marek   +4 more
core   +1 more source

Supported Co catalysts prepared as thin films by magnetron sputtering for sodium borohydride and ammonia borane hydrolysis [PDF]

open access: yes, 2014
Supported Co catalysts were prepared for sodium borohydride and ammonia borane hydrolysis by magnetron sputtering for the first time under different conditions. Ni foam was selected as support.
Arzac, G. M.   +4 more
core   +2 more sources

Terminal uranium(V)-nitride hydrogenations involving direct addition or Frustrated Lewis Pair mechanisms

open access: yesNature Communications, 2020
Despite their importance as mechanistic models for Haber Bosch ammonia synthesis from N2 and H2, high oxidation state terminal metal-nitrides are notoriously unreactive towards H2.
Lucile Chatelain   +8 more
doaj   +1 more source

Destabilization of Boron-Based Compounds for Hydrogen Storage in the Solid-State: Recent Advances

open access: yesEnergies, 2021
Boron-based materials have been widely studied for hydrogen storage applications. Examples of these compounds are borohydrides and boranes. However, all of these present some disadvantages that have hindered their potential application as hydrogen ...
Carlos A. Castilla-Martinez   +3 more
doaj   +1 more source

Positional disorder in ammonia borane at ambient conditions [PDF]

open access: yes, 2014
We solve a long-standing experimental discrepancy of NH$_3$BH$_3$, which---as a molecule---has a threefold rotational axis, but in its crystallized form at room temperature shows a fourfold symmetry about the same axis, creating a geometric ...
Giannozzi, P.   +2 more
core   +2 more sources

Increasing Hydrogen Density with the Cation-Anion Pair BH4−-NH4+ in Perovskite-Type NH4Ca(BH4)3

open access: yesEnergies, 2015
A novel metal borohydride ammonia-borane complex Ca(BH4)2·NH3BH3 is characterized as the decomposition product of the recently reported perovskite-type metal borohydride NH4Ca(BH4)3, suggesting that ammonium-based metal borohydrides release hydrogen gas ...
Pascal Schouwink   +4 more
doaj   +1 more source

Rh/Ti3C2Tx MXene catalyst: its synthesis and application in the decomposition of ammonia borane to hydrogen

open access: yes上海师范大学学报. 自然科学版, 2021
The two-dimensional transition metal carbides and carbonitrides (MXene) based catalyst has excellent catalytic activity for the hydrolysis and hydrogen production reaction.
ZHANG Qingxiao   +4 more
doaj   +1 more source

Photolysis of Diborane at 1849 Å [PDF]

open access: yes, 1962
The photolysis of diborane at 1849 Å has been studied in a specially constructed, internal‐type mercury‐vapor lamp. The products have been found to be H_2, B_(4)H_(10), B_(5)H_(11), and, at low pressures, a —BH— polymer.
Kreye, W. C., Marcus, R. A.
core   +1 more source

van der Waals epitaxy of monolayer hexagonal boron nitride on copper foil : growth, crystallography and electronic band structure [PDF]

open access: yes, 2015
We investigate the growth of hexagonal boron nitride (h-BN) on copper foil by low pressure chemical vapour deposition (LP-CVD). At low pressure, h-BN growth proceeds through the nucleation and growth of triangular islands.
Asensio, Maria-Carmen   +8 more
core   +1 more source

Dipole Moment of Ammonia-Borane [PDF]

open access: yesThe Journal of Chemical Physics, 1958
The dipole moment of ammonia-borane, H3NBH3, has been measured as 4.9 debye units in dioxane solution; the results are discussed briefly.
Weaver, J. R.   +2 more
openaire   +2 more sources

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