Results 81 to 90 of about 3,729 (203)

Main Group Metals in Redox Catalysis

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
Main group metal redox catalysis is emerging as a credible alternative to transition metal chemistry. Elements from groups 13 to 15 now enable diverse catalytic manifolds, driven by ligand design and control of electronic structure. This review highlights recent advances, key design principles, and remaining challenges, positioning main group metals as
Olympia Mouriki   +2 more
wiley   +1 more source

Supported ammonia borane decomposition through enhanced homopolar B–B coupling

open access: yes, 2018
The thermolytic decomposition of ammonia borane (AB) is known to proceed through the polymeric coupling reaction between –BH3 and –NH3 sites of multiple ammonia borane molecules, which results in the release of hydrogen and other by-products, e.g ...
Animesh Hajari   +3 more
core   +1 more source

Ammonia Borane: An Extensively Studied, Though Not Yet Implemented, Hydrogen Carrier

open access: yesEnergies, 2020
Ammonia borane H3N−BH3 (AB) was re-discovered, in the 2000s, to play an important role in the developing hydrogen economy, but it has seemingly failed; at best it has lagged behind.
Umit Bilge Demirci
doaj   +1 more source

Synthesis of Amorphous‐Crystalline Mixture Boron Nitride for Balanced Resistive Switching Operation

open access: yesSmall, EarlyView.
An amorphous–crystalline mixture BN (acm‐BN) is synthesized through low‐pressure chemical vapor deposition, achieving balanced resistive switching with low SET voltage and stable RESET. High‐resolution transmission electron microscopy reveals that BN films are fully amorphous at 930 °C, a mixed amorphous–crystalline phase is achieved at 990 °C.
Kyung Jin Ahn   +8 more
wiley   +1 more source

Role of Pressure in the Growth of Hexagonal Boron Nitride Thin Films from Ammonia-Borane

open access: yes, 2016
We analyze the optical, chemical, and electrical properties of chemical vapor deposition (CVD) grown hexagonal boron nitride (h-BN) using the precursor ammonia-borane (H3N–BH3) as a function of Ar/H2 background pressure (PTOT).
Ximeng Liu (2820076)   +17 more
core   +1 more source

Influence of morphology of hollow silica–alumina composite spheres on their activity for hydrolytic dehydrogenation of ammonia borane

open access: yesJournal of Advanced Ceramics, 2017
Hollow silica–alumina composite spheres were prepared by a polystyrene (PS) template method using various amounts of PS suspension. Homogeneous hollow spheres prepared using 40 g were found to be with a diameter of about 300 nm in scanning electron ...
Naoki Toyama   +7 more
doaj   +1 more source

Dual Functionality of a Plasmonic Gold Photocatalyst in the Reversible Dehydrogenation / Hydrogenation of N‐Heterocycles

open access: yesSmall, EarlyView.
A new hybrid plasmonic material, Au@COF, serves as a recyclable photocatalyst for the light‐mediated dehydrogenation and hydrogenation of N‐Heterocycles, where simply adjusting the reaction conditions allows control over the reaction mechanism, marking a notable breakthrough for hydrogen storage.
Alba Sorroche   +4 more
wiley   +1 more source

Dimethyl‐, Diethyl‐, and Propylene Carbonates: An Emerging Class of Green Solvents for Organic Synthesis

open access: yesThe Chemical Record, EarlyView.
This review highlights recent advances in the use of organic carbonates, dimethyl carbonate (DMC), diethyl carbonate (DEC), and propylene carbonate (PC), as solvents in organic synthesis. Based on over seventy studies from the past 6 years, it shows their application in different organic reaction types, emphasizing their role in safer and more ...
Gabriela T. Quadros   +5 more
wiley   +1 more source

Cobalt hollow nanospheres: controlled synthesis, modification and highly catalytic performance for hydrolysis of ammonia borane

open access: yes, 2017
Size tunable cobalt hollow nanospheres with high catalytic activity for the ammonia borane (AB) hydrolysis have been synthesized by using the solvothermal method.
Xu, Jie   +7 more
core   +1 more source

Hydrogen Generation via Catalytic Ammonia Borane Hydrolysis: A Patent Overview

open access: yes
Hydrogen is one of the clean energies that will play an important role in energy selection for the coming low-carbon society. Ammonia borane (NH3BH3, abbreviated hereafter as AB) is considered as a promising hydrogen storage material due to its high ...
Koyo, Matsuda
core   +1 more source

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