Results 51 to 60 of about 6,173 (179)
The Stabilization of High‐Nitrogen Systems: 10 Catenated Nitrogen Chain
Improving the understanding of high‐nitrogen materials. ABSTRACT High‐nitrogen materials have attracted intense interest in recent decades due to their unique chemical, physical, and biological properties. Stabilizing high‐nitrogen materials is often challenging as they become more unstable with increasing nitrogen catenation and nitrogen mass ...
Nicholas F. Scherschel +3 more
wiley +1 more source
Bis(2-pyridylmethyl)ammonium perchlorate
The title compound, C14H18N3+·ClO4−, a perchlorate salt of the monoprotonated form of bis(2-pyridylethyl)amine, has a structure in which one of the two H atoms on the amine N atom forms hydrogen bonds to the two pyridyl N atoms in a chelating fashion, while the second H atom on the amine is also used in hydrogen bonding to a perchlorate O atom.
Ray J. Butcher +2 more
openaire +1 more source
Overcoming Interfacial Hurdles in Solid‐State Aluminum Batteries for Safe and Energy‐Dense Storage
Solid‐state aluminum batteries (SSABs) promise high energy density and intrinsic safety but face severe solid–solid interfacial challenges. This review reveals the three core hurdles—anode passivation, cathode contact loss, and electrolyte grain boundary resistance and discusses strategies including artificial interphases, alloying, and composite ...
Yunlei Wang +5 more
wiley +1 more source
Integrative in silico and in vitro screening of small molecules targeting RNA
Abstract Targeting structured RNA elements with small molecules has emerged as a promising yet technically challenging strategy for antiviral drug discovery. Here, we present a comprehensive and experimentally validated workflow for the integrative in silico and in vitro screening of RNA‐binding small molecules.
Sabrina Toews +2 more
wiley +1 more source
ABSTRACT We report on the synthesis and characterization of 3‐(2‐(2‐azidoethoxy)ethoxy)‐4‐nitro‐1,2,5‐oxadiazole (NFPEG2N3), which is a liquid nitrofurazanyl ether that was designed to be an energy‐rich plasticizer for glycidyl azide polymer (GAP)‐ and nitrocellulose (NC)‐based formulations.
P. Lieber +3 more
wiley +1 more source
Purification and Properties of Polyvinyl Nitrate and Its Compatibility With Solid Oxidizers
ABSTRACT Polyvinyl nitrate (PVN) is a nitrate‐ester energetic binder that can be produced directly from polyvinyl alcohol—a cheap commodity feedstock—thereby offering potential cost and supply‐chain advantages over binders based on nitrocellulose and other specialty polymers.
Stephen Spice +3 more
wiley +1 more source
ObjectiveA method was developed to simultaneously determine chlorate and perchlorate in vegetables and fruits using ultra-performance liquid chromatography-triple quadrupole/linear ion trap mass spectrometry (UPLC-Qtrap MS).MethodsThe chlorate and ...
FANG Xiaoli +4 more
doaj +1 more source
On the Alternative Protonation of Heterocyclic Michler´s Ketone Analogues
Bis(5‐aminothionyl)ketones exhibit a significant bathochromic shift in the UV–vis absorption spectrum and form deeply violet proton adducts under acidic conditions. NMR spectroscopy and quantum chemical calculations confirm that O‐protonation occurs. In contrast, protonation of the amino groups in Michler´s ketone and the heterocyclic aza moieties in ...
Evgenia Dmitrieva +2 more
wiley +1 more source
This review highlights recent advances in the use of organic carbonates, dimethyl carbonate (DMC), diethyl carbonate (DEC), and propylene carbonate (PC), as solvents in organic synthesis. Based on over seventy studies from the past 6 years, it shows their application in different organic reaction types, emphasizing their role in safer and more ...
Gabriela T. Quadros +5 more
wiley +1 more source
“Innocent” Electrolytes Can Influence Organic Electrosynthetic Selectivity
Organic electrosynthesis has emerged as a powerful strategy for leveraging inexpensive and abundant electricity in organic synthesis, but understanding the role of inert supporting electrolyte is largely unexplored. This article investigates cobalt‐based metal–carbon bond homolysis and elucidates how supporting electrolytes influence reaction rates ...
Zachary A. Nguyen +7 more
wiley +1 more source

