Ambient Hydrocarbonylation of Olefins Enabled by Visible‐Light
Advanced Science, EarlyView.A novel photo‐induced methodology for hydrocarbonylation has been established, resolving the inherent conflicts between competitive olefin and CO insertion in traditional methods that necessitate harsh conditions. Accordingly, an efficient and versatile hydrocarbonylation of olefins enabled by visible‐light irradiation under ambient conditions has been
Hongchi Liu, Tianze Zhang, Hanmin Huang
wiley +1 more source
One‐Pot Amidation/C─H Halogenation by an Efficient Electrochemical Cascade
Angewandte Chemie, EarlyView.A sustainable electrochemical cascade enables the one‐pot synthesis of regioselectively halogenated N‐aryl amides from readily available amines and acyl halides under mild conditions. The method merges amidation and C─H halogenation in a single operational step, delivering broad substrate scope, high selectivity, and scalability, and provides an ...
Sudipta Ponra +8 more
wiley +2 more sources
Advanced Energy Materials, Volume 15, Issue 11, March 18, 2025.The impact of polyaniline insertion on the atomic orbitals and electronic structure of vanadium oxide anode is systematically investigated for the first time. The electrode exhibits an outstanding capacity and unprecedent long‐term cycling life, owing to the electron transition to the V 3dxy state and the enhanced diffusion kinetics.
Yue Zhang +6 more
wiley +1 more source
Chemical polymerization of aniline in phenylphosphinic acid [PDF]
Journal of the Serbian Chemical Society, 2005 The chemical polymerization of aniline was performed in phenylphosphinic acid (APP) medium using ammonium peroxidisulfate as the oxidizing agent, at 0 ºC and 25 ºC. The yield of polyaniline (PANI) was about 60–69 %. The polymerization process required an
NICOLETA PLESU +3 more
doaj
Automated analysis of oxidative metabolites [PDF]
, 1974 An automated system for the study of drug metabolism is described. The system monitors the oxidative metabolites of aromatic amines and of compounds which produce formaldehyde on oxidative dealkylation.
Furner, R. L.
core +1 more source
Photoacoustic detection of stimulated emission pumping in p-difluorobenzene [PDF]
, 1984 Photoacoustic detection has been used to monitor a stimulated emission pumping process in p‐difluorobenzene. Using the Ã^(1)B_(2u)5^1 state as an intermediate, several vibrational levels of the ground electronic state were populated.
Kuppermann, A. +2 more
core
Aniline and Beyond: A Multifaceted Case Study for a Bildung-Focused Chemical Education
OrganicsIn the chemical education field, the Johnstone’s triangle represents three learning levels (symbolic, macroscopic, and molecular) needed for students. Afterwards, Mahaffy suggested a tetrahedron model based on this triangle, where the top represents the ...
Teresa Celestino
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Azine polymers and process for preparing the same Patent [PDF]
, 1970 Synthesis of azine polymers for heat shields by azine-aromatic aldehyde ...
Dalelio, G. F.
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Scope and Mechanistic Study of the Ruthenium-Catalyzed \u3cem\u3eortho\u3c/em\u3e-C−H Bond Activation and Cyclization Reactions of Arylamines with Terminal Alkynes [PDF]
, 2005 The cationic ruthenium hydride complex [(PCy3)2(CO)(CH3CN)2RuH]+BF4- was found to be a highly effective catalyst for the C−H bond activation reaction of arylamines and terminal alkynes.
Yi, Chae S., Yun, Young
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Ultraviolet relaxation dynamics of aniline, N, N-dimethylaniline and 3,5-dimethylaniline at 250 nm [PDF]
, 2015 Dave Townsend +9 more
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