Results 81 to 90 of about 30,335 (240)

Bridged Pyrroloindole‐CAYC‐Gold Complexes: Harnessing Weak Secondary Intramolecular Au···H−C(sp3) Interactions in Gold(I) Catalysis

Angewandte Chemie, EarlyView.
We present a new class of electronically and sterically hindered N‐heterocyclic carbenes, referred to as bridged cyclic (amino)ylide carbene (bCAYC), where 9H‐pyrrolo[1,2‐a]indole acted as carbene core and diaryl sulfonium as ylide partner. Corresponding bCAYC‐Au(I) exhibits a weak secondary intramolecular Au···H−C(sp3) interaction as a secondary ...
Sourav Sekhar Bera, Anurag Kumar, Pengcheng Gao, Sanghamitra Das, Roger Lalancette, Roman Szostak, Michal Szostak   +6 more
wiley   +2 more sources

Synthesis and in vitro/in silico evaluation of the antimalarial activity of potential amino-quinoline derivatives

European Journal of Medicinal Chemistry Reports
In this study, a series of N-arylamino-7-chloroquinolines were synthesized via an alkylation reaction involving aniline derivatives (2) and 4,7-dichloroquinoline (1).
Moussa Touré, Abdoulaye Gassama, Oumar Sambou, Christian Cavé, Sandrine Cojean   +4 more
doaj   +1 more source

Dual Effect of Steric Hindrance in Non‐Aqueous Amine Absorbents: Navigating the Trade‐Off Between Kinetics and Thermodynamics for Efficient CO2 Capture

Advanced Science, EarlyView.
This study elucidates how steric hindrance in amines creates a dual effect in CO2 capture: it thermodynamically favors the reaction by shifting the pathway from carbamate to alkyl carbonate formation, increasing capacity and lowering regeneration heat, while simultaneously slightly slowing the kinetics.
Xiaoyi Gao, Bin Xu, Xi Tang, Muyi Li, Cong Luo, Fan Wu, Xiaoshan Li, Liqi Zhang, Wen Chen   +8 more
wiley   +1 more source

Scalable Access to N‑Acylindole Linkages: Enabling the Synthesis of Antitrypanosomal Noncanonical Cyclic Peptides for Chagas Disease

Angewandte Chemie, EarlyView.
A gram‐scale supply of bulbiferamide A, which features a rare N‐acylindole linkage and possesses potent inhibitory activity against Trypanosoma cruzi epimastigotes (IC50 = 4.1 µM)—the causative parasite of Chagas disease—was successfully achieved. Moreover, the cyclization strategy developed in this study facilitated the synthesis of noncanonical ...
Jie Zhang, Hugh Nakamura
wiley   +2 more sources

Synthesis of New Asymmetrical Pyromellitdiimide and Their Amic Acids Containing Heterocyclic Unit

Ibn Al-Haitham Journal for Pure and Applied Sciences, 2017
This work involves the synthesis and characterization of  asymmetrical  pyromellitdiimide derivatives [VII]a-f  by four sequences steps reaction .
Jumbad H. Tomma, Kadhim M. Lazim AL-Aliawi, Imad T. Ali   +2 more
doaj  

Ambient Hydrocarbonylation of Olefins Enabled by Visible‐Light

Advanced Science, EarlyView.
A novel photo‐induced methodology for hydrocarbonylation has been established, resolving the inherent conflicts between competitive olefin and CO insertion in traditional methods that necessitate harsh conditions. Accordingly, an efficient and versatile hydrocarbonylation of olefins enabled by visible‐light irradiation under ambient conditions has been
Hongchi Liu, Tianze Zhang, Hanmin Huang
wiley   +1 more source

Bis(silylene)‐Mediated N═N Bond Scission of Diazo Compounds

Angewandte Chemie, EarlyView.
The carborane‐based bis(silylene) enables unprecedented N═N bond scission in diazodiarylmethanes. While xanthene‐ and aniline‐based scaffolds promote end‐on addition with partial N═N activation, the carborane‐based variant uniquely achieves complete N═N bond scission of Ar2C═N═N compounds, resulting in isolable disilicon nitride imino species.
Yun Xiong, Shenglai Yao, Matthias Driess
wiley   +2 more sources

Comparison of Dissolved Air Flotation Process for Aniline and Penicillin G Removal From Aqueous Solutions

پزشکی بالینی ابن سینا, 2017
Introduction: The presence of antibiotics due to toxicity and sustainability as well as organic compounds as a combination of hard biodegradable wastewater is an undesirable issue in many industries.
F Kord Mostafapoor, Sh Ahmadi, D Balarak, S Rahdar   +3 more
doaj  

White Light Emission from a Simple Mixture of Fluorescent Organic Compounds

Scientific Reports, 2019
Three fluorescent organic compounds—furocoumarin (FC), dansyl aniline (DA), and 7-hydroxycoumarin-3-carboxylic acid (CC)—are mixed to produce almost pure white light emission (WLE).
Norfatirah Muhamad Sarih, Peter Myers, Anna Slater, Ben Slater, Zanariah Abdullah, Hairul Anuar Tajuddin, Simon Maher   +6 more
doaj   +1 more source

Orbital and Electrical Dual Function of Polymer Intercalant for Promoting NH4+ Storage in Vanadium Oxide Anode

Advanced Energy Materials, Volume 15, Issue 11, March 18, 2025.
The impact of polyaniline insertion on the atomic orbitals and electronic structure of vanadium oxide anode is systematically investigated for the first time. The electrode exhibits an outstanding capacity and unprecedent long‐term cycling life, owing to the electron transition to the V 3dxy state and the enhanced diffusion kinetics.
Yue Zhang, Zihang Huang, Lei Lei, Hua Fan, Xu Han, Hui Li, Tianyi Ma   +6 more
wiley   +1 more source