Results 61 to 70 of about 20,997 (254)

Anion templated surface assembly of a redox-active sensory rotaxane

Chemical Communications, 2007
Anion templation is used to assemble novel redox-active bis-ferrocene functionalised rotaxane self-assembled monolayers (SAMs) on to gold electrode surfaces; after template removal, the unique SAM rotaxane binding domain is capable of selectively sensing chloride ions electrochemically.
Bayly, SR, Gray, T, Chmielewski, M, Davis, J, Beer, P   +4 more
openaire   +2 more sources

Atomically Dispersed Ni Site Catalysts Accelerating Sluggish Sulfur Redox Kinetics in Nonaqueous Zn‐S Batteries

Advanced Functional Materials, EarlyView.
An atomically dispersed Ni catalyst featuring Ni‐N4 coordination is developed as a sulfur host for nonaqueous Zn─S batteries. This configuration modulates the electronic structure to lower activation barriers during rate‐limiting steps and promotes a robust ZnF2‐rich cathode‐electrolyte interphase, thereby accelerating sulfur redox kinetics ...
Junhyuk Ji, Dongwoo Kim, Nuri Moon, Daehwan Kim, Keon Kim, Nahyung Kim, Young Yong Kim, Won Bae Kim   +7 more
wiley   +1 more source

Formulating long-cycle and high-rate lithium-rich manganese-based cathodes by surface-modification strategy coupling defect-engineering

Nano Research
Triggering the anionic redox reactions at high voltage is an effective approach to boost the capacity of Li-rich layered oxides. However, the irreversible lattice oxygen release at high voltage and sluggish ion kinetics remain conundrums.
Yanpeng Liu, Haobo Du, Jianyuan Wang, Ting Liu, Yunxiang Guo, Kun Zhu, Xiaoyi Hou, Shanglong Peng   +7 more
doaj   +1 more source

Charge‐Tunable Coacervate Micelles for Separator Engineering in Lithium‐Sulfur Batteries

Advanced Functional Materials, EarlyView.
A separator engineering strategy based on charge‐tunable complex coacervate core micelles (C3Ms) is presented to form an ion‐selective layer regulating polysulfide transport in Li–S batteries. The micelles enable uniform adsorption onto commercial polypropylene separators and infiltration throughout the internal pore network, suppressing polysulfide ...
Yongsheng Zhang, J. R. Andrade Aguirre, Julien Es Sayed, Chongyang Jiang, Yuxuan Zhang, Xiaolong He, Yinyu Xiang, Yutao Pei, Xiangping Zhang, Petra Ruldolf, Marleen Kamperman, Giuseppe Portale   +11 more
wiley   +1 more source

Confinement‐Engineered Thermally Programmed Ion‐Gating Separator for Decoupling Thermal–Electrochemical Feedback in High‐Energy Lithium‐Ion Batteries

Advanced Functional Materials, EarlyView.
A new phase‐change material encapsulated membrane offers more thermal resilience stability and safety than the conventional separators for batteries. ABSTRACT Thermal runaway in lithium‐ion batteries arises from the intrinsic coupling between heat generation and ion transport, yet conventional shutdown separators primarily rely on passive pore collapse
Sumedha Rajpoot, Wei‐Nien Su, Sheng‐Chiang Yang, Yu Chun Huang, Wahyu Fiqih Virdiansyah, Ashok Ranjan, Han‐Hsuan Hsieh, Chia‐Lung Hsieh, Yu‐Wei Li, Yosef Nikodimos, Zabish Bilew Muche, Yu Jen Liang, Chia‐Chi Wang, Chih‐Ching Liu, Gao‐Jhih Liang, Chun‐Chen Yang, She‐Huang Wu, Bing Joe Hwang   +17 more
wiley   +1 more source

Construction of Stable Oxygen Redox by Electrochemical Activation O–TM–Se in Nickel‐Rich Layered Oxides for Lithium‐Ion Batteries

Small Structures
The irreversible oxygen redox and structural degradation of LiNi0.8Co0.1Mn0.1O2 (NCM811) at a 4.5 V high voltage cause a severe decline in cycling performance for lithium‐ion batteries.
Youqi Chu, Yongbiao Mu, Lingfeng Zou, Yan Hu, Shaowei Kang, Haixiang Ren, Meisheng Han, Qing Zhang, Lei Wei, Lin Zeng   +9 more
doaj   +1 more source

Dual‐Layer Conducting and Redox Polymer Bioanodes for Synergistic Enhancement of Microbial Extracellular Electron Transfer

Advanced Functional Materials, EarlyView.
A hybrid PEDOT/Fc‐LPEI conducting/redox polymer bioanode synergistically improves microbial extracellular electron transfer (EET) in Shewanella oneidensis MR‐1. The dual‐layer interface delivers 18‐fold higher current output and 27‐fold greater charge collected than bare carbon felt, highlighting an effective strategy for high‐performance ...
Shenghan Gu, Saman Azhari, Kuniaki Nagamine, Takeo Miyake, Gábor Méhes   +4 more
wiley   +1 more source

Encoded Cell‐Material Interactions to Reroute Cytokine Signaling for Regenerative Medicine

Advanced Healthcare Materials, EarlyView.
We present native MATRIX (Material Activated To Regulate Inducible gene eXpression), a co‐engineered material‐cell platform. Surfaces functionalized with antibodies for endogenous soluble ligands (e.g., IL‐1β or IL‐6) capture and immobilize ligands for presentation to a cognate, engineered synthetic Notch receptor, releasing a transcription factor (TF)
Zachary M. Eidman, Jhanvi Sharma, Joanne C. Lee, Nicholas F. Schulze, Hannah J. Brien, Kevin C. Corn, Marjan Rafat, Jonathan M. Brunger   +7 more
wiley   +1 more source

Interplay between oxygen redox and interfacial stability of Li-rich positive electrodes in sulfide-based all-solid-state batteries

Nature Communications
Understanding and manipulating the interplay between lattice oxygen redox and interfacial stability is critical for realizing the full potential of lithium-rich manganese-based oxide positive electrodes in all-solid-state lithium batteries.
Yuqi Wu, Fucheng Ren, Cheng Li, Chuanjing Xu, Huanran Wang, Jianrong Lin, Hanyan Wu, Qin Wang, Yiming Zou, Weidong Zhang, Guozhen Wei, Hongxin Lin, Ying Lin, Zhenyu Wang, Zhengliang Gong, Yong Yang   +15 more
doaj   +1 more source

Spiro‐Phenothiazine Hole‐Transporting Materials: Unlocking Stability and Scalability in Perovskite Solar Cells

Advanced Materials, EarlyView.
Fluorene‐functionalized spiro‐phenothiazine (PTZ‐Fl) exhibits strong Li+ affinity and thermal stability, enabling a PCE of 25.75% in small‐area cells and 22.07% in 25 cm2 modules. Under ISOS‐L3 conditions, PTZ‐Flbased devices retain over 80% efficiency after 1000 hours, demonstrating superior stability and scalability compared to spiro‐OMeTAD for next ...
Javier Urieta‐Mora, Seung Ju Choi, Jaeki Jeong, Silvia Orecchio, Inés García‐Benito, Manuel Pérez‐Escribano, Joaquín Calbo, Likai Zheng, Minseop Byun, Seyeong Song, Gi‐Hwan Kim, Shaik M. Zakeeruddin, Seog‐Young Yoon, Yimhyun Jo, Agustín Molina‐Ontoria, Enrique Ortí, Nazario Martín, Michael Grätzel   +17 more
wiley   +1 more source