Results 211 to 220 of about 233,059 (308)

Stimuli‐Responsive Hierarchical Structuring Controls Survival and Programs Hydrogelation of Supramolecular Metallofibers

Advanced Materials, EarlyView.
Aqueous Zn(II) Salphen metallofibers decorated with PNIPAM undergo reversible, multi‐stimuli‐responsive hierarchical bundling. This higher‐order structuring kinetically stabilizes the otherwise fragile assemblies against dilution, acidic hydrolysis, and transmetallation, enables selective sorting of responsive fibers, and programs hydrogelation at ...
Merlin R. Stühler, László Mérai, Kai Ludwig, Rainer Haag, Quinn A. Besford, Alex J. Plajer   +5 more
wiley   +1 more source

Decoupling X-Ray Absorption and Emission: Ionic TADF Scintillators With Heavy-Atom-Functionalized Organic Anions. [PDF]

Angew Chem Int Ed Engl
Liang D, He Q, Jia JH, Cai XB, Hu SB, Lu CZ.   +5 more
europepmc   +1 more source

Above Room Temperature Ferroelectricity in Epitaxially Strained KTaO3

Advanced Materials, EarlyView.
Through precise epitaxial engineering, the cubic and paraelectric KTaO3${\rm KTaO}_3$ is transformed into a robust ferroelectric. By leveraging lattice‐mismatched substrates to apply controlled epitaxial strain, a stable ferroelectric ground‐state is achieved with a transition temperature as high as 475 K, establishing KTaO3${\rm KTaO}_3$ as a highly ...
Tobias Schwaigert, Salva Salmani‐Rezaie, Sankalpa Hazra, Utkarsh Saha, Maya Ramesh, Aiden Ross, Betül Pamuk, Long‐Qing Chen, David A. Muller, Darrell G. Schlom, Venkatraman Gopalan, Kaveh Ahadi   +11 more
wiley   +1 more source

Relaxation of magnetization in Dy₂ and Tb₂ dimers with single-electron lanthanide-lanthanide bonds: the effect of cage perturbation and its ultimate symmetry. [PDF]

Chem Sci
Felipe de Souza Barbosa M, Yang W, Wang Y, Velkos G, Avdoshenko SM, Liu F, Popov AA.   +6 more
europepmc   +1 more source

Resolving Nanoscale Heterogeneities in Lead Halide Perovskites Through Low‐Dose Concurrent 4D‐STEM‐EDX Mapping

Advanced Materials, EarlyView.
Mixed‐cation lead mixed‐halide perovskites suffer from structural instabilities linked to nanoscale heterogeneity. To probe this non‐destructively, a low‐dose, concurrent 4D‐STEM and EDX methodology has been developed. Examining a (FA0.83Cs0.17)Pb(I0.8Br0.2)3 film revealed a complex mosaic of coexisting crystal structures. Crucially, local deficiencies
Jinseok Ryu, Alexandra A. Sheader, Mohsen Danaie, David G. Hopkinson, Katherine E. MacArthur, Nakita K. Noel, Christopher S. Allen   +6 more
wiley   +1 more source

Synthesis, structural analysis and reactivity of alkynyl sulfide anions.

Inorg Chem Front
Mondal S, Le Dé Q, Santos Oliveira DA, Rodrigues Silva D, De Feudis A, Bickelhaupt FM, Gessner VH.   +6 more
europepmc   +1 more source

PFAS removal by ultra-low loads of a metal-organic cage. [PDF]

Chem Sci
Juárez-Rosales RA, Sharif L, Jancik V, Khosravi H, Gembicky M, Hernández Sánchez R, Percástegui EG.   +6 more
europepmc   +1 more source

Hydrophobic MFI‐Type Zeolites via Alkali‐Cation‐Induced Defect Healing: Implications for Adsorbent and Catalyst Design

Advanced Materials, EarlyView.
Sub‐stoichiometric amounts of Na+ or K+ enhance defect healing during Silicalite‐1 (MFI) and TS‐1 calcination by promoting Si–O–Si annealing and healing framework vacancies. The resulting defect‐free zeolites are more hydrophobic and show improved butanol/water separation and improved activity and selectivity in the epoxidation of 1‐hexene, offering a ...
Christos Kanteler, Pau Ferri, Francisco Javier Escobar‐Bedia, Álvaro Mayoral, Alejandro Vidal‐Moya, Richard Kendra, Chen Lei, Miguel Palomino, Fernando Rey, Lukáš Grajciar, Christopher James Heard, Pedro Serna, Mercedes Boronat, Cristina Martínez, Manuel Moliner   +14 more
wiley   +1 more source

Anionic solvation reconstruction stabilizes interfacial chemistry for high-temperature and high-voltage Li metal batteries. [PDF]

Nat Commun
Shi Z, Thomas S, Melinte G, Canlas CG, Guo D, Lei Y, El-Demellawi JK, Mansour N, Bakr OM, Mohammed OF, Alshareef HN.   +10 more
europepmc   +1 more source

Gold‐Stabilized Copper Enables Anodic Hydrogen Evolution for Ultralow‐Voltage CO‐to‐Ethylene Electrolysis

Advanced Materials, EarlyView.
Gold‐stabilized copper suppresses hydroxide‐driven deactivation during anodic hydrogen evolution from furfural. Pairing this low‐potential anode with CO‐to‐ethylene electroreduction enables sub‐1 V operation at 400 mA cm−2, high single‐pass CO conversion, and co‐production of ethylene, furoic acid, and a separate hydrogen stream.
Sungjin Park, Hengzhou Liu, Heejong Shin, Hafiz Ghulam Abbas, Loann Bonnenfant, Ke Xie, Hyeon Seok Lee, Fatemeh Arabyarmohammadi, Jianan Erick Huang, Panos Papangelakis, Peiying Wang, Ali Shayesteh Zeraati, Jiheon Kim, Roham Dorakhan, David Sinton, Xiaopeng Liu, Wenzhen Li, Byoung‐hoon Lee, Edward H. Sargent   +18 more
wiley   +1 more source