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Tritium migration in tritiated anisole
Journal of the American Chemical Society, 1982Experimental studies have been reported of reactions involving the phenyl cation as an intermediate where the results obtained are most easily explained in terms of 1,2 hydrogen shifts in the intermediate ion. Our purpose here is to present an alternative interpretation, supported by MINDO/3 calculations, that avoids the implied conclusion that the ...
Michael J. S. Dewar, Charles H. Reynolds
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Photoaddition of maleimide to anisole
Journal of the Chemical Society, Perkin Transactions 1, 1978Irradiation in the maleimide–anisole charge-transfer band gives three isomeric 2 : 1 adducts which result formally from initial 1,2-, 2,3-, and 3,4-additions to the aromatic ring followed by Diels–Alder addition of a second maleimide molecule. The additions are strongly inhibited by the strong proton donor trifluoroacetic acid, yet are markedly ...
Derek Bryce-Smith +2 more
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1996
Publisher Summary Anisole, a compound easily produced by methylation of phenolate, has chemical and physical characteristics, low toxicity and low cost which make it worth being systematically examined by the chemists working either on synthesis or applications.
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Publisher Summary Anisole, a compound easily produced by methylation of phenolate, has chemical and physical characteristics, low toxicity and low cost which make it worth being systematically examined by the chemists working either on synthesis or applications.
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The vibrational spectrum of anisole
Spectrochimica Acta Part A: Molecular Spectroscopy, 1983Abstract The infrared and Raman spectra of C6H5OCD3, C6D5OCH3 and C6D5OCD3 have been recorded in the liquid state. Vibrational assignments have been made and values for most of the fundamental vibrations have been obtained and correlated with those of C6H5OCH3. Studies of the ultraviolet absorption spectrum have provided gas-phase data on a number of
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