Results 21 to 30 of about 65,353 (256)

Developing simple boranes as phase transfer catalysts for nucleophilic fluorination using CsF [PDF]

open access: yes, 2021
Despite the general high fluorophilicity of boron, simple organoboranes such as BEt3 and 3,5-(CF3)2C6H3–BPin are shown herein for the first time, to our knowledge, to be effective phase-transfer catalysts for the fluorination of organohalides with CsF ...
Sven, Kirschner   +4 more
core   +1 more source

MATERIALS FOR FLUORINE GENERATOR ANODE ASSEMBLIES [PDF]

open access: yes, 1956
Corrosion of anode assembly materials in fluorine generators is pronounced, therefore, selection of the proper materials for construction is important. Several metals and alloys have been tested for corrosion resistance when anodic in a fluorine test cell. In general, copper, copper alloys and magnesium alloys offer the best corrosion resistance.
R Simmons   +3 more
openaire   +1 more source

Methodologies for selective electrophilic fluorination [PDF]

open access: yes, 2004
Chapter 1 Chapter 1 contains a discussion of the effects of the introduction of fluorine atoms into organic molecules. A review of electrophilic fluorination reactions which have been reported recently, from the viewpoint of selectivity is given. Chapter
Nakano, Takashi
core  

Electrospun Wood‐Derived Biopolymers as Electrodes in Electrochemical Energy Storage Technologies

open access: yesAdvanced Functional Materials, EarlyView.
Electrospinning transforms wood‐derived cellulose and lignin into architecturally defined, binder‐free carbon electrodes with tuneable porosity and functionality. This review shows how fibre design enables decoupled charge and mass transport, enhancing performance across battery systems, while identifying key challenges in spinnability, scalability ...
Michael W. Thielke   +3 more
wiley   +1 more source

Spatially Regulated Silicon Clusters in Trimodal Composite Anodes for High‐Energy Lithium‐Ion Batteries

open access: yesAdvanced Functional Materials, EarlyView.
A trimodal anode architecture spatially regulates silicon clusters within confined interstitial environments formed by graphite and contorted hexabenzocoronene. This confinement suppresses silicon aggregation and localized stress while enabling efficient Li‐ion transport, achieving high‐capacity, stable lithium‐ion batteries.
Jeongmi Joo   +11 more
wiley   +1 more source

Electrolytic Partial Fluorination of Organic Compounds.71. Highly Diastereoselective Anodic Fluorination of Sulfides Having Oxygen-Containing Heterocyclic Groups

open access: yes, 2016
Diastereoselective anodic fluorination of sulfides having various oxygen-containing heterocyclic substituents such as 2-furanyl, 1,3-dioxolanyl, 2,2-dimethyl-1,3-dioxolanyl, 2-spirocyclohexyl-1,3-dioxolanyl, 2-spiroadamantyl-1,3-dixolanyl, and 1,3 ...
Toshio Fuchigami (2073130)   +1 more
core   +2 more sources

Microreactors and other technologies for direct fluorination [PDF]

open access: yes, 2002
Quinoline/ 2H-chromen-2-one and derivatives thereof, have been found to undergo electrophilic substitution by elemental fluorine in concentrated sulfuric acid as reaction medium.
Holling, Darren
core  

Electroytic Partial Fluorination of Organic Compounds. 52. Regio- and Diastereoselective Anodic Fluorination of Thiazolidines

open access: yes, 2016
Anodic fluorination of N-benzoyl, N-acethyl-, and N-formylthiazolidine derived from l-cysteine was carried out in dimethoxyethane (DME) and acetonitrile containing various supporting fluoride salts using an undivided cell.
Seiichiro Higashiya (2440132)   +4 more
core   +1 more source

Oligoethylene Glycol Side‐Chain Engineering of Y6‐Derived Nonfullerene Acceptors for Thermally Induced Spontaneous Pseudo‐Planar Heterojunction Organic Photodetectors

open access: yesAdvanced Functional Materials, EarlyView.
OEG‐functionalized Y6‐derived acceptors induce thermally driven vertical phase separation, enabling pseudo‐planar heterojunction organic photodetectors. The resulting PM6:YTEG‐4F and PM6:YTEG‐4Cl organic photodetectors suppress dark current density by approximately 260‐fold and 210‐fold, respectively, while maintaining efficient photoresponse ...
Se Jeong Park   +11 more
wiley   +1 more source

Electrophilic fluorination at saturated carbon [PDF]

open access: yes, 2000
Chapter 1 - Chapter 1 contains a discussion of the preparation and properties of elemental fluorine. A review of the use of elemental fluorine as a selective fluorinating in organic chemistry is given and the preparation and use of other selective ...
Parsons, Mandy
core  

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