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Determination of iron by anodic stripping voltammetry
Journal of Electroanalytical Chemistry, 1970Summary A chemical exchange reaction between ferric iron and bismuth-EDTA at pH 4.0 is used to determine iron by anodic stripping voltammetry. The rotating electrode was a highly polished glassy carbon disc, coated in situ with mercury by the addition of mercuric ions to the sample solution. No other common metal ion enters into the exchange reaction,
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A contribution to the use of chelating agents in anodic stripping voltammetry
Talanta, 1971The E(p)/(2), values of the ions Pb(2+), Bi(3+), Cu(2+), Cd(2+), Tl(+) were determined by means of cyclic voltammetry in solutions of acetate and Britton-Robinson buffers and in solutions containing EDTA and DCTA. DCTA was then utilized in the determination of small amounts of bismuth, down to 10(-7)M, in the presence of 10(4) times as much lead, and ...
L, Zieglerová, K, Stulík, J, Dolezal
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MEASURING BIOAVAILABLE COPPER USING ANODIC STRIPPING VOLTAMMETRY
Environmental Toxicology and Chemistry, 1996AbstractSince speciation can affect bioavailability and toxicity of copper in aquatic systems, accurate predictions of effects of bioavailable forms require detection and/or measurement of these forms. To develop an approach for measurement of bioavailable copper, a copper sulfate solution (CuSO4·3Cu(OH)2·H2O) was used in 10-d aqueous and sediment ...
Emily Deaver, John H. Rodgers
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Underpotential deposition and anodic stripping voltammetry at mesoporous microelectrodes
The Analyst, 2005Using the technique of liquid crystal templating a series of high surface area mesoporous platinum microelectrodes was fabricated. The underpotential deposition of metal ions at such electrodes was found to be similar to that at conventional platinum electrodes. The phenomena of underpotential deposition, in combination with the intrinsic properties of
Pablo Lozano, Sanchez, Joanne M, Elliott
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Application of sequential injection analysis to anodic stripping voltammetry
Talanta, 1997Sequential injection analysis (SIA) technique has been applied to anodic stripping voltammetry (ASV). The sample and reagent volumes can easily be controlled by SIA. The technique also allows plating of the mercury film on-line and therefore substantially reduces generation of mercury containing waste.
A, Ivaska, W W, Kubiak
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Anodic Stripping Voltammetry Using a Vibrating Electrode
Electroanalysis, 2007AbstractThis work proposes a vibrating microwire electrode as working electrode in stripping voltammetry. The vibration was found to maintain a constant and thin (1–2 μm) diffusion layer during the deposition step. The electrode vibration eliminated the need for external stirring of the solution, thus facilitating in situ detection in the environment ...
Conrad S. Chapman +1 more
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Selective method for the determination of gold by anodic stripping voltammetry
Analytical and Bioanalytical Chemistry, 1996A highly selective method for the deter- mination of gold by anodic stripping voltammetry is described. For preconcentration a glassy carbon electrode, activated by deposition of small amounts of gold before the measurement, is proposed. The Au(3+) reduction process at such an electrode is effective starting with the potential +0.4 V vs.
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Arsenic (III) Detection with Underpotential Deposition and Anodic Stripping Voltammetry
ChemElectroChem, 2021Richard Compton, Danlei Li
exaly
Trace analysis by anodic stripping voltammetry
Journal of Electroanalytical Chemistry (1959), 1963M. Ariel, U. Eisner
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