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Electrochemical and CMT measurements of the anomalous dissolution of nickel in solutions containing oxygen

Electrochimica Acta, 1997
In addition to single nickel crystals also nickel samples produced by dc and pr (pulse-reversal) plating were examined. As previously reported the true rate of dissolution of nickel in solutions containing oxygen was found to be as much as three times the electrochemical rate at the corrosion potential. When passivation was approached (spontaneously or
G. Bech-Nielsen   +2 more
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A new selective chemical dissolution procedure for chemical speciation studies of anomalous iridium in geological samples

Chemical Geology, 1990
Abstract A new selective chemical dissolution procedure for geological samples has been developed: six components were separated, i.e. carbonate, metal, sulfide, oxide, silicate and HF-insoluble residue. A series of experimental parameters, e.g. reagent types, temperature, time and pH-value, in dissolving the various phases has been investigated. The
Kong Ping, Chai Chifang
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Anomalous temperature dependence of photoluminescence spectra from InAs/GaAs quantum dots grown by formation–dissolution–regrowth method

Chinese Physics B, 2017
Two kinds of InAs/GaAs quantum dot (QD) structures are grown by molecular beam epitaxy in formation–dissolution–regrowth method with different in-situ annealing and regrowth processes. The densities and sizes of quantum dots are different for the two samples.
Guan-Qing Yang   +4 more
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Anomalously rapid transport of matter during dissolution of solid clusters of He3 in separated He3–4He mixtures

Low Temperature Physics, 1998
The kinetics of growth and dissolution of a new phase during phase separation and homogenization of solid He3–4He mixtures is studied experimentally. It is found that both these processes have different kinetics, while homogenization is ensured by an anomalously rapid transport of matter in the crystal.
A. N. Gan’shin   +5 more
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Electrochemistry of Active Chromium: Part 1— Anomalous Corrosion and Products of Chromium Dissolution in Deaerated Sulfuric Acid

Corrosion, 2004
Chromium corroding in deaerated aqueous solution of sulfuric acid (H2SO4; pH 1 to 3) produces Cr(II) and Cr(III) ions simultaneously in the ratio 7:1, as well as H2. The corrosion potentials of electrochemically activated chromium are determined by the electrochemical processes as expected according to the Wagner-Traud model. However, the real rates of
D.M. Dražić, J.P. Popić
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Anodic Dissolution of Metals—Anomalous Valence

1974
When metals are dissolved anodically in aqueous and nonaqueous media, the weight of metal dissolved is sometimes greater than that calculated from Faraday’s law assuming normal oxidation states. Among several metals of industrial importance, Al, Be, Cd, Fe, Pb, Mg, Ti, and Zn exhibit this phenomenon.
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The Anomalous Dissolution of Iron As a Result of the Chemical Conjugation between Iron Ionization and Hydrogen Evolution

Protection of Metals, 2001
Based on an idea about common intermediate particles, a physicochemical model of iron dissolution and hydrogen evolution is proposed. According to the model, the independence of the dissolution rate of a cathodically polarized metal of the potential is a particular case of chemically conjugate anodic–cathodic reactions.
I. D. Zartsyn   +2 more
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An Experimental and PM3 Semiempirical Quantum-chemical Investigation of Anomalous Aluminium Dissolution in Proton-donor Solvents Containing HCl

Mendeleev Communications, 1995
An anomalous chemical mechanism of aluminium dissolution has been experimentally determined in electrolytes containing HCI based on proton-donor solvents (methanol, ethanol, propanol, water), and this mechanism has been explained by a new theoretical approach based on the comparison of the work function of aluminium with the electron affinity of ...
Naum M. Gontmakher   +3 more
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On the existence of an anomalously high dissolution rate in films of non-Newtonian liquids with short contact times

Journal of Non-Newtonian Fluid Mechanics, 1981
Abstract It has been shown that the dissolution rate of gypsum in films of dilute sodium carboxymethylcellulose (SCMC) solutions is anomalously high compared with theoretical predictions. Two possible explanations of this phenomenon are discussed: either the coefficient of diffusivity in these solutions is much greater than it is in water, or the ...
G. Peev, A. Nikolova
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The anomalous diffusion processes “dissolution-precipitation” of THE γ′ Phase Ni3Al in AN Fe–Ni–Al alloy during low-temperature deformation

Materials Letters, 2016
Abstract An anomalous deformation-induced dissolution of the intermetallics Ni 3 Al in the matrix of austenitic Fe–Ni–Al alloy has been revealed in experiment at cryogenic temperatures (down to 77 K) under high pressure torsion. The observed phenomenon is explained as the result of deformation-stipulated migration of interstitial atoms from a ...
V.V. Sagaradze   +5 more
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