Results 201 to 210 of about 39,546 (266)

The Interplay of Single Ion Anisotropy and Magnetic 3 d‐4 f Interactions in VIII2LnIII2 Butterfly Complexes

open access: yesChemistryEurope, EarlyView.
The 3d–4f coupling constants and relative angles between distinct anisotropy axes in butterfly‐shaped VIII2LnIII2 (Ln=Y, Tb−Yb) metal‐organic molecular complexes are determined using combined high‐field EPR spectroscopy and magnetisation studies. The observed chemical trend sheds light on the electronic exchange mechanism and highlights the important ...
Jan Arneth   +8 more
wiley   +1 more source

TiNiSi‐Type ALiAu (A = Ca, Sr, Ba, Eu, Yb) Compounds: Alternative Use of “Excess” Electrons

open access: yesChemistry – A European Journal, EarlyView.
Excess electrons distinguish the bonding in ALiAu (A = Yb, Ca, Eu, Sr, Ba), a new series of intermetallic compounds crystallizing in TiNiSi type. According to bonding analysis, these metallic phases are classified as aurides containing polycations with multiatomic bonding between A, Li, and Au . Abstract New TiNiSi‐type compounds ALiAu (A = Ca, Sr, Ba,
Peter Höhn   +8 more
wiley   +1 more source

Extending MIEZE spectroscopy towards thermal wavelengths

open access: yesJournal of Applied Crystallography, Volume 55, Issue 6, Page 1424-1431, December 2022., 2022
A modulation of intensity with zero effort (MIEZE) setup is proposed for high‐resolution neutron spectroscopy at momentum transfers up to 3 Å−1, energy transfers up to 20 meV and an energy resolution in the microelectronvolt range using both thermal and cold neutrons.A modulation of intensity with zero effort (MIEZE) setup is proposed for high ...
Johanna K. Jochum   +3 more
wiley   +1 more source

The Relevance of Non‐axiality and Low‐lying Excited States for Slow Magnetic Relaxation in Pentagonal‐bipyramidal Erbium(III) Complexes Probed by High‐frequency EPR

open access: yesChemistry – A European Journal, Accepted Article.
High‐frequency/high‐field electron paramagnetic resonance studies on a series of seven‐coordinate pentagonal‐bipyramidal (PBP) erbium(III) complexes Er(DAPMBH/H2DAPS)X (H2DAPMBH = 2,6‐diacetylpyridine bis‐4‐methoxy benzoylhydrazone, H4DAPS = 2,6‐diacetylpyridine bis‐(salicylhydrazone)) demonstrate the effects of different apical ligands (X = (H2O)Cl (1)
Jan Arneth   +5 more
wiley   +1 more source

Efficient data reduction for time‐of‐flight neutron scattering experiments on single crystals

open access: yesJournal of Applied Crystallography, Volume 55, Issue 6, Page 1514-1527, December 2022., 2022
In neutron scattering experiments, data sets with different statistical significance are collected. A new method is presented to efficiently calculate the weights of single‐crystal time‐of‐flight measurements, and to add together the various contributions.Event‐mode data collection presents remarkable new opportunities for time‐of‐flight neutron ...
Andrei T. Savici   +7 more
wiley   +1 more source

Oxidation‐Deformylation Cascade Catalyzed By a Mononuclear Copper Complex

open access: yesChemistry – A European Journal, EarlyView.
A bioinspired copper complex is able to catalyze two successive oxidative steps of alcohol conversion in the presence of hydrogen peroxide under mild conditions: (i) alcohol oxidation to aldehyde and (ii) aldehyde deformylation. Isotopic effects on the reaction rates indicate that hydrogen atom abstraction is rate limiting for both steps.
Yongxing Wang   +8 more
wiley   +1 more source

Preparation of pyrite concentrate powder from the Thackaringa mine for quantitative phase analysis using X‐ray diffraction

open access: yesJournal of Applied Crystallography, Volume 55, Issue 6, Page 1572-1582, December 2022., 2022
A method for performing accurate quantitative phase analysis using X‐ray powder diffraction of pyrite concentrate mineral samples from the Thackaringa mine has been devised. The sample preparation optimization process is described. Grain size reduction suitable for analysis by the Rietveld method was achieved using ball milling.The quantitative phase ...
Hamish McDougall   +5 more
wiley   +1 more source

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