Results 1 to 10 of about 506,658 (155)

The Apparent Activation Energy of a Novel Low-Calcium Silicate Hydraulic Binder. [PDF]

open access: yesMaterials (Basel), 2021
In this work, the apparent activation energy (Ea) of a novel low-calcium binder was, for the first time, experimentally determined, using a calorimetric approach. Additionally, a correlation between the Ea, measured at the acceleration period with the C/S ratio of the hydration product is proposed.
Antunes M   +5 more
europepmc   +4 more sources

On Apparent Activation Energy of Structure Sensitive Heterogeneous Catalytic Reactions [PDF]

open access: yesCatalysis Letters, 2019
The notion of apparent activation energy is discussed in relation to structure sensitivity of complex heterogeneous catalytic reactions comprising several steps. The cases of nonuniform surfaces (intrinsic and induced) are considered, showing that the apparent activation energy depends on the cluster size and surface coverage.
Dmitry Yu Murzin
exaly   +2 more sources

Analysis and theory of gas transport in microporous sol-gel derived ceramic membranes [PDF]

open access: yes, 1995
Sol-gel modification of mesoporous alumina membranes is a very successful technique to improve gas separation performance. Due to the formed microporous top layer, the membranes show activated transport and molecular sieve-like separation factors.
Burggraaf, A.J.   +4 more
core   +7 more sources

In situ surface coverage analysis of RuO2-catalysed HCl oxidation reveals the entropic origin of compensation in heterogeneous catalysis [PDF]

open access: yes, 2012
In heterogeneous catalysis, rates with Arrhenius-like temperature dependence are ubiquitous. Compensation phenomena, which arise from the linear correlation between the apparent activation energy and the logarithm of the apparent pre-exponential factor ...
Farra, R.   +10 more
core   +2 more sources

Using Apparent Activation Energy as a Reactivity Criterion for Biomass Pyrolysis [PDF]

open access: yesEnergy & Fuels, 2016
The reactivity of chemically isolated lignocellulosic blocks, namely, α-cellulose, holocellulose, and lignin, has been rationalized on the basis of the dependence of the effective activation energy (Eα) upon conversion (α) determined via the popular isoconversional kinetic analysis, Friedman’s method.
Carrier, Marion   +3 more
openaire   +3 more sources

Interpretation of the apparent activation energy of glass transition

open access: yesJournal of Physics Communications, 2021
Abstract The temperature dependence of the viscosity of glass is a major concern in glass research. The apparent activation energies obtained from Arrhenius plots often show unusual values larger than bond energies, which makes the interpretation of the activation energy difficult.
openaire   +2 more sources

On the Apparent Activation Energy for Clustering in Dilute Al-Zn Alloys [PDF]

open access: yes, 1978
The clustering phenomenon was observed when dilute Al-Zn alloys were annealed at temperatures higher than the solvus of the G.P.zones. In this report the apparent activation energy for clustering is estimated and compared with the experimental results ...
Kobayashi, Toshinori   +2 more
core   +1 more source

Apparent activation energy during surface evolution by step formation and flow [PDF]

open access: yes, 2006
During growth and etching by step flow as examples of anisotropic surface processing the apparent activation energy of the growth/etch rate depends on orientation, increasing gradually as a principal, terrace-rich surface is approached. This behaviour is
Cheng, D.   +3 more
core   +2 more sources

Effect of amylose content on estimated kinetic parameters for a starch viscosity model. [PDF]

open access: yes, 2013
The apparent viscosity profile of starches during gelatinization varies with different amylose content. This study focused on the influence of amylose content on the kinetic parameters of a starch viscosity model for corn starches.
Dolan, Kirk D., Sulaiman, Rabiha
core   +1 more source

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