Results 141 to 150 of about 1,086,479 (244)

Interspecies Biofilm Dynamics Among Staphylococci: Inflammatory Contributions to Chronic Rhinosinusitis

open access: yesInternational Forum of Allergy &Rhinology, EarlyView.
ABSTRACT Introduction Staphylococcus species are frequently isolated from the sinonasal niche of chronic rhinosinusitis (CRS) patients. While Staphylococcus aureus is often associated with recalcitrant CRS, Staphylococcus epidermidis and Staphylococcus lugdunensis are largely deemed commensal.
Sintayehu Ambachew   +8 more
wiley   +1 more source

Azole γ‐Peptides Helix Switching via Heterocycle Substitutions

open access: yesAngewandte Chemie, EarlyView.
Heterocycle substitution in azole‐based γ‐amino acids enables control over the helical shape of heterocyclic γ‐peptides. S↔N permutation in thiazole residues switches a canonical 9‐helix into a flexible helix exhibiting discontinuous hydrogen bonding.
Samantha Chaise   +10 more
wiley   +2 more sources

Zero‐Valent Nickel Stabilized in Surface‐Supported Metal–Organic Chains

open access: yesAngewandte Chemie International Edition, EarlyView.
9,10‐Dicyanoanthracene coordinates Ni atoms on Ag(100) to form metal–organic chains that stabilize zero‐valent Ni(0) (d10) centers with quasi‐one‐dimensional metal–ligand electronic coupling. ABSTRACT The stabilization of zero‐valent nickel Ni(0) centers in extended coordination networks remains a major challenge due to their pronounced reactivity and ...
Simone Mearini   +10 more
wiley   +1 more source

The Missing Link in Ferrocenophane Chemistry: Isolation of a Carba[1]Ferrocenophane

open access: yesAngewandte Chemie International Edition, EarlyView.
The synthesis and isolation of a crystalline carba[1]ferrocenophane is reported. A single carbon atom is the smallest bridging motif yet incorporated into a ferrocenophane, resulting in a dihedral angle between the cyclopentadienyl ring planes of 36.7°, which is the highest angular deflection from ferrocene's coplanarity observed so far.
Aylin Feuerstein   +5 more
wiley   +1 more source

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