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Preparation of Polymer Brushes by Surface-Initiated ARGET ATRP
Advanced Materials Research, 2013This paper firstly summarized the latest research progress on the polymer brushes preparation by surface-initiated ARGET ATRP polymerization. It mainly includes the surface modifications of inorganic substrate (silicon dioxide and carbon nanotubes), and the organic substrate (cellulose and polymer microspheres).
Xiao Meng Chu +3 more
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Synthesization and Characterization of Lignin-graft-Poly (Lauryl Methacrylate) via ARGET ATRP
International Journal of Biological Macromolecules, 2022Lignin as an abundant biological macromolecule isolated from the plant cell wall, and it cannot be efficiently utilized until suitable modifications to its structures were made. Therefore, we proposed a strategy to prepare an all biomass-based Lignin-graft-poly(Lauryl methacrylate, LMA) by grafting LMA monomers on the organosolv lignin through ARGET ...
Min, Wu +5 more
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Journal of Nanoscience and Nanotechnology, 2016
Oligo(ethylene glycol) methacrylate (OEGMA) was polymerized from a polymerization initiator-presenting gold substrate by Activator ReGenerated by Electron Transfer Atom Transfer Radical Polymerization (ARGET ATRP) in water. Compared with the normal surface-initiated ATRP (SI-ATRP), SI-ARGET ATRP of OEGMA proceeded smoothly in the presence of air with L-
Bong Soo, Lee +4 more
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Oligo(ethylene glycol) methacrylate (OEGMA) was polymerized from a polymerization initiator-presenting gold substrate by Activator ReGenerated by Electron Transfer Atom Transfer Radical Polymerization (ARGET ATRP) in water. Compared with the normal surface-initiated ATRP (SI-ATRP), SI-ARGET ATRP of OEGMA proceeded smoothly in the presence of air with L-
Bong Soo, Lee +4 more
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Controlled Polymerization of Protic Ionic Liquid Monomer by ARGET‐ATRP and TERP
Macromolecular Rapid Communications, 2014The direct synthesis of structurally well‐defined protic polymeric ionic liquid (PIL) with controlled molecular weight and molecular weight distribution is examined using N,N‐diethyl‐N‐(2‐methacryloylethyl) ammonium bis(tri‐fluoromethylsulfonyl)imide (DEMH‐TFSI) as a monomer.
Yasuyuki, Nakamura +6 more
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Protein–polymer hybrids: Conducting ARGET ATRP from a genetically encoded cleavable ATRP initiator
European Polymer Journal, 2013Abstract Protein–polymer hybrids are an important class of biomaterials. Described is the preparation of a genetically incorporated a non-canonical amino acid (nCAA) containing an ester linked atom transfer radical polymerization (ATRP) initiator, followed by a controlled “grafting from” polymerization.
Saadyah E. Averick +5 more
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Numerical simulation and parametric study of solution ARGET ATRP of styrene
Computational Materials Science, 2016Abstract This paper uses an ARGET ATRP mathematical modeling to study the solution polymerization of styrene. Differently from previous published works, a detailed parametric study was performed in order to verify how chemical species behave throughout the polymerization process and to provide a numerical tool for analysis, optimization and process ...
João G.D. Preturlan +2 more
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Predictive Tool for Design and Analysis of ARGET ATRP Grafting Reactions
Macromolecules, 2017Solving a comprehensive, yet simple, reaction model for describing the activators regenerated by electron transfer (ARGET)–atom transfer radical polymerization (ATRP) reaction cascade, we show that the molar ratios of transition metal catalyst to initiator and reducing agent to catalyst are critical parameters in the ARGET ATRP mechanism, with optimal ...
John J. Keating IV +2 more
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Hydrophobic modification of wood via surface-initiated ARGET ATRP of MMA
Applied Surface Science, 2012Abstract To convert the hydrophilic surface of wood into a hydrophobic surface, the present study investigated activators regenerated by electron transfer for atom transfer radical polymerization (ARGET ATRP) as a method of grafting methyl methacrylate (MMA) onto the wood surface.
Yanchun Fu, Haipeng Yu, Yixing Liu
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Postmodification of PS-b-P4VP Diblock Copolymer Membranes by ARGET ATRP
Langmuir, 2014The surfaces of polystyrene-block-poly(4-vinylpyridine) (PS-b-P4VP) diblock copolymer membranes were modified in order to obtain polymer brushes by using surface-initiated activators regenerated by electron transfer atom transfer radical polymerization (ARGET ATRP).
Damla, Keskin +4 more
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A ratiometric electrochemical biosensor based on ARGET ATRP for detection of HER2 gene
TalantaHuman epidermal growth factor receptor 2 (HER2), a common proto-oncogene, is overexpressed in a subset of breast cancer patients. It is essential to track HER2 expression for early breast cancer diagnosis. Herein, a ratiometric electrochemical biosensor for detection of HER2 based on activators generated by electron transfer for atom transfer radical ...
Aozi Feng +6 more
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