Results 231 to 240 of about 102,681 (307)

Modular Assembly of Dynamic Polymer Networks From Heteroaffinity Cross‐Links to Multivalent Proteins

open access: yesAngewandte Chemie, EarlyView.
This study develops a method to modularly assemble oligomeric binding proteins, like streptavidin, using heterobifunctional cross‐linkers that have both a strong‐ and a weak‐affinity binding moiety. These dynamic cross‐linkers enable the assembly of polymer networks with unique meta‐stable nonequilibrium topologies, and that exhibit chemically tunable ...
Tianyue Dai   +6 more
wiley   +1 more source

Acceptorless Dehydrogenative Polymerization

open access: yesAngewandte Chemie, EarlyView.
Acceptor‐less dehydrogenative polymerization (ADP) enables the atom‐economic step‐growth synthesis of different type of polymers directly from simple alcohols, releasing H2 as the sole by‐product. This review outlines the mechanistic foundations, catalytic systems, and emerging polymer architectures of ADP, highlighting its potential as a sustainable ...
Xin Liu   +2 more
wiley   +1 more source

Orbital‐Selective Modulation of Spatial pz‐s Hybridization for Enhanced Photocatalytic H2 Evolution: Insights From NiSe@ReS2+x Cocatalyst

open access: yesAngewandte Chemie, EarlyView.
Spatial orbital‐selective modulation engineering is proposed as a strategy to optimize cocatalyst design, enhance photocatalytic activity, and provide novel insights into the interactions between active sites and adsorbates, as well as catalytic mechanisms.
Duoduo Gao   +5 more
wiley   +1 more source

Ligand‐Intercalated MOFs Enable Reaction‐Pathway Engineering in Biomass Electrooxidation via Steric and π‐Electronic Microenvironment Control

open access: yesAngewandte Chemie, EarlyView.
Through ligand length and π‐electron density modulation, metal–organic frameworks (MOFs) improve mass transport and hydrogen atom transfer (HAT), thus improving biomass electrooxidation. ABSTRACT Controlling reaction pathways in electrocatalytic biomass upgrading remains challenging because mass transport, substrate adsorption, and elementary kinetics ...
Junjie Chen   +12 more
wiley   +1 more source

Pregnancy is linked to faster epigenetic aging in young women. [PDF]

open access: yesProc Natl Acad Sci U S A
Ryan CP   +8 more
europepmc   +1 more source

Harnessing Support‐Dependent Hydrogen Spillover for Ni‐Based CO2 Hydrogenation

open access: yesAngewandte Chemie, EarlyView.
Hydrogen spillover can be harnessed for Ni‐based CO2 hydrogenation via support‐dependent pathways. Hydrogen spillover propagating to surfaces promotes catalysis through two distinct mechanisms. On moderately reducible supports, it rapidly removes poisoning oxygen species (*O) from Ni nanoparticles.
Kazuki Shun   +3 more
wiley   +1 more source

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