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Nature Chemistry, 2022 The following organizations are thanked for financial support: the Ministerio de Ciencia e Innovación (MICINN, project number PID2020-113711GB-I00) and the Generalitat de Catalunya (project number 2017SGR0039)
Solà i Puig, Miquel
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Global Aromaticity at the Nanoscale [PDF]
Nature Chemistry, 2019 Aromaticity can be defined by the ability of a molecule to sustain a ring current when placed in a magnetic field. Hückel's rule states that molecular rings with [4n + 2] π-electrons are aromatic, with an induced magnetization that opposes the external field inside the ring, whereas those with 4n π-electrons are antiaromatic, with the opposite ...
Michel Rickhaus +8 more
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Journal of Molecular Structure, 2014 We report experimental and theoretical evidences for supramolecular aromaticity as a new concept to be widely used in researches about molecular crystals. CSD survey regarding frequently encountered resonance-assisted H-bonds (RAHBs) in formic acid, formamide, formimidamide, formic acid-formamide, and formamide-formimidamide dimers shows that ...
Karabiyik, Hande +2 more
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Aromatic chloroosmacyclopentatrienes
National Science Review, 2022 ABSTRACT Aromatic metallacycles are of considerable current interest. Reported aromatic metallacycles are mainly those with carbon, nitrogen, oxygen and sulfur. In this work, we report the synthesis and characterization of aromatic chloroosmacyclopentatrienes, which represent the first structurally confirmed metallaaromatic with a ...
Zhenwei Chu +7 more
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Visualisation of chemical shielding tensors (VIST) to elucidate aromaticity and antiaromaticity [PDF]
, 2021 Aromaticity is a central concept in chemistry, pervading areas from biochemistry to materials science. Recently, chemists also started to exploit intricate phenomena such as the interplay of local and global (anti)aromaticity or aromaticity in non‐planar
Florian, Glöcklhofer +5 more
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, 2023 Aromaticity is one of the most deeply rooted concepts in chemistry. But why, if two-thirds of existing compounds can be classified as aromatic, is there no consensus on what aromaticity is? σ−, π−, δ−, spherical, Möbius, or all-metal aromaticity… why are
Lazzeretti, Paolo +35 more
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Aromaticity-Enhanced pH-Responsive Electrochemiluminescence of Cyclopentadienols
, 2022 Due to significantly tackling the problems of aggregation-caused quenching and water insolubility, aggregation-induced emission electrochemiluminescence (AIE-ECL) has emerged as a research highlight in aqueous detection and sensing. Herein, we reported a
Yanhong Xu +11 more
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Hydrogenated polycyclic aromatic hydrocarbons: isomerism and aromaticity
Physical Chemistry Chemical Physics, 2020 A simple model based on adjacency matrices is introduced to study the stability of hydrogenated polycyclic aromatic hydrocarbons. Aromaticity governs their relative stability having the most stable isomers the higher number of non-hydrogenated rings.
Paula Pla +3 more
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Quantifying the electronic dimension of global aromaticity in macrocycles
, 2023 Characteristic magnetic shielding patterns are commonly associated with ring currents, and therefore aromaticity, in large molecular structures. However, the relationship between ring currents and aromaticity is controversial, and this problem is not ...
David, Bradley +2 more
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