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Singlet Fission in a Pyrrole-Fused Cross-Conjugated Skeleton with Adaptive Aromaticity.
Journal of the American Chemical Society, 2020Singlet fission (SF) materials hold the potential to raise power conversion efficiency of solar cell by reducing thermalization of high-energy excited-states.
Long Wang +7 more
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Chemistry – A European Journal, 2014
AbstractNo organic molecules with electron affinities near or above those of halogens are known. We show for the first time that aromaticity rules can be used to design molecules with electron affinities far exceeding those of halogen atoms either by tailoring the ligands of cyclopentadienyl or by multiple benzoannulations of cyclopentadienyl in ...
Child, Brandon +3 more
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AbstractNo organic molecules with electron affinities near or above those of halogens are known. We show for the first time that aromaticity rules can be used to design molecules with electron affinities far exceeding those of halogen atoms either by tailoring the ligands of cyclopentadienyl or by multiple benzoannulations of cyclopentadienyl in ...
Child, Brandon +3 more
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Global Aromaticity in Macrocyclic Polyradicaloids: Hückel's Rule or Baird's Rule?
Accounts of Chemical Research, 2019Aromaticity is one of the most important concepts in organic chemistry to understand the electronic properties of cyclic π-conjugated molecules. Over a century, different aromaticity rules have been developed and validated.
Chunchen Liu +4 more
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Chemistry – An Asian Journal, 2018
AbstractAromatic aminocatalysis refers to transformations that employ aromatic amines, such as anilines or aminopyridines, as catalysts. Owing to the conjugation of the amine moiety with the aromatic ring, aromatic amines demonstrate distinctive features in aminocatalysis compared with their aliphatic counterparts.
Jian Lv +4 more
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AbstractAromatic aminocatalysis refers to transformations that employ aromatic amines, such as anilines or aminopyridines, as catalysts. Owing to the conjugation of the amine moiety with the aromatic ring, aromatic amines demonstrate distinctive features in aminocatalysis compared with their aliphatic counterparts.
Jian Lv +4 more
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Accounts of Chemical Research, 2007
The first example of a family of related aromatic metallacycles has been synthesized, and the physical and chemical properties of its individual members have been investigated. The metallacyclic rings in these compounds are, in general, constructed from pentadienyl- or heteropentadienyliridium precursors via C-H bond activation processes. The molecules
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The first example of a family of related aromatic metallacycles has been synthesized, and the physical and chemical properties of its individual members have been investigated. The metallacyclic rings in these compounds are, in general, constructed from pentadienyl- or heteropentadienyliridium precursors via C-H bond activation processes. The molecules
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Carbohydrate Research, 2006
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Mårten, Jacobsson +2 more
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AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Mårten, Jacobsson +2 more
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Unconventional Aromaticity in Organometallics: The Power of Transition Metals.
Accounts of Chemical Research, 2019Aromaticity, one of the most fundamental concepts in chemistry, has attracted considerable attention from both theoreticians and experimentalists. Much effort on aromaticity in organometallics has been devoted to metallabenzene and derivatives.
Dandan Chen, Qiong Xie, Jun Zhu
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Dehalogenation of Aromatics by Nucleophilic Aromatic Substitution
Environmental Science & Technology, 2014Nucleophilic aromatic substitution has been implicated as a mechanism for both the biotic and abiotic hydrodehalogenation of aromatics. Two mechanisms for the aqueous dehalogenation of aromatics involving nucleophilic aromatic substitution with hydride as a nucleophile are investigated using a validated density functional and continuum solvation ...
Daniel, Sadowsky +2 more
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“Carbo-aromaticity” and novel carbo-aromatic compounds
Chemical Society Reviews, 2015Recent advances in experimental and theoretical studies ofcarbo-benzene derivatives, along with the proposition of a generalization of the definition of aromaticity to the two-membered π-rings of triple bonds, suggest relevance for the notion of “carbo-aromaticity”.
Kévin, Cocq +3 more
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