Results 61 to 70 of about 40,114 (276)

Aromatics

open access: yes, 2021
A start is made with the family of the para-dihalobenzenes, including the key system p-dichlorobenzene + p-dibromobenzene. Special attention is given to the melting behaviour of mixed materials prepared by zone levelling. The family of the dihalobenzenes is followed by the group of the 2-R-substituted naphthalenes which includes naphthalene itself (R = 
Van Der Linde, P. R., Oonk, H. A. J.
openaire   +1 more source

C2α‐carbanion‐protonating glutamate discloses tradeoffs between substrate accommodation and reaction rate in actinobacterial 2‐hydroxyacyl‐CoA lyase

open access: yesFEBS Open Bio, EarlyView.
Enzymes of the 2‐hydroxyacyl‐CoA lyase group catalyze the condensation of formyl‐CoA with aldehydes or ketones. Thus, by structural adaptation of active sites, practically any pharmaceutically and industrially important 2‐hydroxyacid could be biotechnologically synthesized. Combining crystal structure analysis, active site mutations and kinetic assays,
Michael Zahn   +4 more
wiley   +1 more source

Structure, Stability, Edge States and Aromaticity of Graphene Ribbons

open access: yes, 2008
We determine the stability, the geometry, the electronic and magnetic structure of hydrogen-terminated graphene-nanoribbons edges as a function of the hydrogen content of the environment by means of density functional theory.
A. Marco Saitta   +7 more
core   +3 more sources

The Effect of varying Ground-state Aromaticity on the First Molecular Electronic Hyperpolarizabilites of Organic Donor-Acceptor Molecules [PDF]

open access: yes, 1993
A series of compounds of the form 4-dimethylaminophenyl–polyene–acceptor, where the polyene ranges from nothing to all-trans-1,3,5-hexatriene and the acceptor is 2-nitrovinyl, formyl, or 2,2-dicyanovinyl has been prepared and their β values measured by ...
Cheng, Lap-Tak   +2 more
core   +1 more source

Establishing an assay to evaluate d‐amino acid oxidase enzyme kinetics and inhibition using WST‐8 redox dye

open access: yesFEBS Open Bio, EarlyView.
This study investigated a novel WST‐8‐based assay for evaluating d‐Amino acid oxidase (DAO) inhibitors. We confirmed its effectiveness using known inhibitors and found that uremic toxins possess relatively weak inhibitory activity compared to existing drugs.
Kahoko Miyake   +4 more
wiley   +1 more source

Flux and Seasonality of Dissolved Organic Matter From the Northern Dvina (Severnaya Dvina) River, Russia [PDF]

open access: yes, 2018
Pan‐Arctic riverine dissolved organic carbon (DOC) fluxes represent a major transfer of carbon from land‐to‐ocean, and past scaling estimates have been predominantly derived from the six major Arctic rivers. However, smaller watersheds are constrained to
Bulygina, Ekaterina   +10 more
core   +2 more sources

Evolutionarily divergent DUF4465 domains have a common vitamin B12‐binding function

open access: yesFEBS Open Bio, EarlyView.
We show that DUF4465 family proteins, widespread across bacteria from gut microbiomes, hydrothermal vents, and soil, share a common vitamin B12‐binding function. These augmented β‐jellyroll proteins bind vitamin B12 via extended loops. Our findings establish sequence‐diverse DUF4465 proteins as a widespread class of B12‐binding proteins, highlighting ...
Charlea Clarke   +4 more
wiley   +1 more source

Crystal structures of two unusual, high oxidation state, 16-electron iridabenzenes

open access: yesActa Crystallographica Section E: Crystallographic Communications, 2015
Treatment of carbonyl(1,2-diphenylpenta-1,3-dien-1-yl-5-ylidene)bis(triphenylphosphane)iridium, [IrCO(—C(Ph)=C(Ph)—CH=CH—CH=)(PPh3)2], with either bromine or iodine produced dibromido(1,2-diphenylpenta-1,3-dien-1-yl-5-ylidene)(triphenylphosphine)iridium ...
Daniel T. Chase   +2 more
doaj   +1 more source

The applicability of three-dimensional aromaticity in BiSnn- Zintl analogues [PDF]

open access: yes, 2010
Three-dimensional aromaticity is shown to play a role in the stability of deltahedral Zintl clusters and here we examine the connection between aromaticity and stability.
Castleman, A. W., Jr.   +5 more
core   +2 more sources

CSF Monoamine Metabolites and Cognitive Trajectory in Early Parkinson's Disease

open access: yesAnnals of Clinical and Translational Neurology, EarlyView.
ABSTRACT Background Imaging and postmortem studies indicate that abnormalities in monoaminergic neurotransmission contribute to cognitive impairment in Parkinson's disease (PD). However, it remains uncertain if cerebrospinal fluid (CSF) monoamine metabolites can serve as biomarkers of cognitive decline in early PD.
Jing‐Yu Shao   +7 more
wiley   +1 more source

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