Results 71 to 80 of about 40,114 (276)

Are Metallacyclopentadienes Always Non-Aromatic?

open access: yesChemistry, 2021
Even though metallacyclopentadienes (MCPs) are among the most common metallacycles, their electron delocalization (aromaticity) has received far less attention than other metallacycles, such as metallabenzenes.
Ricardo Casiano-González   +1 more
doaj   +1 more source

Enhanced Gamma Radiation Shielding Using Epoxy Quartz Fabric Composites Reinforced With CoCl2 Microparticles

open access: yesAdvanced Engineering Materials, EarlyView.
The growing demand for lightweight, nontoxic, and multifunctional gamma shielding materials has intensified efforts to find alternatives to conventional lead and aluminum‐based protectants. In this work, we develop epoxy quartz fabric composites reinforced with cobalt chloride (CoCl2) microparticles, fabricated via hand lay‐up with varying filler ...
Summan Urooge   +7 more
wiley   +1 more source

How aromatic dissolved organic matter differs in competitiveness against organic micropollutant adsorption

open access: yesEnvironmental Science and Ecotechnology
Activated carbon is employed for the adsorption of organic micropollutants (OMPs) from water, typically present in concentrations ranging from ng L−1 to μg L−1.
Qi Wang   +10 more
doaj   +1 more source

Reversal of Clar's Aromatic‐Sextet Rule in Ultrashort Single‐End‐Capped [5,5] Carbon Nanotubes

open access: yesChemistryOpen, 2020
The three‐fold HOMO‐LUMO gap oscillation, typical of finite length armchair carbon nanotubes (CNT), has a major effect on the magnetic response of ultrashort, single‐end‐capped [5,5] carbon nanotubes to a perturbing magnetic field parallel to the main ...
Dr. Guglielmo Monaco   +2 more
doaj   +1 more source

Oxidation with a “Stopover” – Stable Zwitterions as Intermediates in the Oxidation of α‐Tocopherol (Vitamin E) Model Compounds to their Corresponding ortho‐Quinone Methides

open access: yesChemistryOpen, 2021
As a prominent member of the vitamin E group, α‐tocopherol is an important lipophilic antioxidant. It has a special oxidation chemistry that involves phenoxyl radicals, quinones and quinone methides.
Dr. Stefan Böhmdorfer   +1 more
doaj   +1 more source

Edge modification of PAHs: the effect of embedded heterocycles on the aromaticity pattern [PDF]

open access: yes, 2015
International audienceAromaticity studies carried out on the condensed model system 2 with different heteroatoms showed that the NICS(1) aromaticity in the five-membered ring correlates with that in the parent five-membered ring having the same ...
Bouit, Pierre-Antoine   +3 more
core   +3 more sources

Impact of Sustainable Binders Based on Lignin and Collagen on the Volume Stability and Mechanical Properties of MgO‐C Refractories with MgO‐C Recyclates

open access: yesAdvanced Engineering Materials, EarlyView.
Collagen hydrolysate is evaluated as a sustainable binder for MgO‐C refractories. Its thermally induced cross‐linking and gas release lead to expansion and cracking in large bricks, but tailored batches with lignin, recyclates, or fine graphite improve the gas release while thermal treatment and stability.
Till M. J. Stadtmüller   +8 more
wiley   +1 more source

Metallo-Anti-aromatic Al4Na4 and Al4Na3- compounds: A theoretical investigation

open access: yes, 2003
We propose a theoretical investigation in this paper to understand the bonding and structural properties of neutral Al4Na4 and anion Al4Na3- clusters.
Kanhere, Dilip. G.   +2 more
core   +1 more source

Synthesis and First Hyperpolarizabilities of Acceptor-substituted β-apo-8’-Carotenal Derived Compounds [PDF]

open access: yes, 1993
The synthesis and second-order nonlinear optical properties of acceptor-substituted biologically derived β-apo-8′-carotenal compounds are reported; electric field-induced second harmonic generation (EFISH) measurements give values of β(0) which are 2–6 ...
Cheng, Lap-Tak   +3 more
core   +1 more source

Development of Sustainable MgO–C Refractories Using MgO–C Recyclates and a Novel Eco‐Friendly Fructose–Tannin Binder Crosslinked With Citric Acid

open access: yesAdvanced Engineering Materials, EarlyView.
This study develops sustainable MgO–C refractories using recycled materials and eco‐friendly fructose–tannin binders. The enhanced performance of citric acid as a cross‐linker and functional additives on mechanical and thermomechanical properties was examined. Characterization included strength tests, immersion trials, and microstructural and inclusion
Dinesh K. Gunasekar   +7 more
wiley   +1 more source

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