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Determining the Association Constant and Adsorption Properties of Ion Pairs in Water by Fitting Surface Tension Data

Langmuir, 2005
Association constants and adsorption parameters of tetraalkylammoniumdodecyl sulfate (TAADS) ion pairs in water were determined. We have analyzed water/air surface tension measurements obtained for mixtures of sodium dodecyl sulfate (SDS) and tetraalkylammonium bromide of increasing chain lengths (TMAB, TEAB, TPAB, and TBAB).
Vincent, Pradines   +3 more
openaire   +2 more sources

Ion Pair Formation in Water. Association Constants of Bolaform, Bisquaternary Ammonium, Electrolytes by Chemical Trapping

The Journal of Physical Chemistry B, 2005
The first and second association constants, K1 and K2, for ion pair formation in aqueous 0.02-3.5 M solutions of bis(trimethyl)-alpha,omega-alkanediammonium halides with variable spacer lengths, 1-n-1 2X (n = 2-4, X = Cl, Br) and bolaform salts and for tetramethylammonium halides (TMAX, X = Cl, Br), K(TMAX), were determined by the chemical trapping ...
Yan, Geng, Laurence S, Romsted
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Redox-Controlled Ion-Pairing Association of Anionic Surfactant to Ferrocene-Terminated Self-Assembled Monolayers

Langmuir, 2015
The redox-induced pairing from aqueous solution of a homologous series of sodium n-alkyl sulfate (NaCnSO4) surfactants of 6, 8, 10, and 12 carbons with gold-tethered self-assembled monolayers (SAMs) of ferrocenyldodecanethiolate (FcC12SAu) is investigated by cyclic voltammetry combined with surface plasmon resonance (SPR) spectroscopy.
Kim-Ly, Nguyen   +2 more
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Trends in Ion Pair Association for Alkali Metal Salts in Nonaqueous Solvents

Transactions of the Kansas Academy of Science (1903-), 1974
For a number of experimental properties of alkali metal salts measured in nonaqueous solvents, the magnitude of the solute parameter undergoes a systematic shift with increasing atomic number of the cation or anion. Representative of the fundamental quantities exhibiting such trends are: (a) the half-wave potentials for alkali metal iodides and ...
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Ion‐pair association and acid–base equilibria in nonaqueous capillary electrophoresis of weakly basic compounds

ELECTROPHORESIS, 2006
AbstractCE in nonaqueous media was used to study the migrating behavior of two weakly basic s‐triazine pesticides and one of their metabolites. The target pesticides were selected to be representative for each of the two main groups: propazine and deethylatrazine for the chloro‐s‐triazines group and ametryn for the methylthio‐s‐triazines group.
Rita, Carabias-Martínez   +4 more
openaire   +2 more sources

The ion-pair association constant of oxalate with fac-tris(2-aminomethylpyridine)cobalt(III)

Polyhedron, 1996
The equilibrium constant K for the ion-pair formation fac-[Co(pic)3]3+ + C2O22− ⇌ fac-[Co(pic)3]3+/C2O42−1 where pic = 2-aminomethylpyridine, has been determined spectrophotometrically at 0.35 M (KCl) ionic strength and 25.0°C, using four different calculation approaches. The best results were obtained when the concentration of the minor component (the
Maria Amélia de Almeida Azzellini   +3 more
openaire   +1 more source

Association of the Ion Pair End-Groups of Halato Telechelic Polymers in Nonpolar Solvents

1985
Halato telechelic polymers (HTP) result from the complete ionization of both ends of telechelic prepolymers. In nonpolar solvents, they form homogeneous gels which upon dilution generally transform into more or less viscous solutions unless they display a phase separation process.
R. Jerome, G. Broze, Ph. Teyssie
openaire   +1 more source

Ion Pair Association in Extreme Aqueous Environments: Molecular-based and Electrical Conductance Approaches

Journal of Solution Chemistry, 2009
We determined by molecular-based simulation the density profiles of the Na+ ⋅⋅⋅Cl− ion-pair association constant in steam environments along three supercritical isotherms to interrogate the behavior of ion speciation in dilute aqueous solutions at extreme conditions.
Ariel A. Chialvo   +4 more
openaire   +1 more source

Ion pair mobility in associated liquid membranes

Analytical Chemistry, 1981
Claudio. Fabiani, Claudia. Cianetti
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Ion-pair association constants in dimethyl sulfoxide

The Journal of Organic Chemistry, 1980
William N. Olmstead   +1 more
openaire   +1 more source

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