Results 151 to 160 of about 1,574,076 (309)

Characterization of the Cubamyces Menziesii Terpenome

ChemBioChem, EarlyView.
The genome of Cubamyces menziesii reveals 18 putative sesquiterpene cyclase genes. These genes are cloned and expressed in Escherichia coli, yielding 10 active enzymes. Using farnesyl diphosphate as substrate, the enzymes are analyzed, and the products characterized after bioconversion, uncovering diverse sesquiterpene structures. This study highlights
Létitia Leydet, Julie Couillaud, Agnès Amouric, Elise Courvoisier‐Dezord, Carole Avesque, Thierry Giardina, Mireille Attolini, Pierre Rousselot‐Pailley, Katia Duquesne, Marie‐Noelle Rosso, Gilles Iacazio   +10 more
wiley   +1 more source

Synthesis of Nucleoside Derivatives by Biomimetic Ester Migration

ChemBioChem, EarlyView.
In tRNA aminoacylated nucleosides represent the central transfer unit of amino acids. An occurring 2′‐3′‐transaminoacylation is biomimetically exploited to successfully synthesize nucleosidic acid esters. This approach can be further expanded on sulfonic acid esters, which has the potential of a broad range of stereo‐ and regio‐controlled modifications
Nathalie J. Kurrle, Christoph J. B. Seifert, Nathalie Hampel, Tamara Rauch, Michael Thoma, Luca V. Parziale, Marian S. R. Ebeling, Dino Berthold, Oliver Trapp   +8 more
wiley   +1 more source

C13‐Deacylase from Nocardioides albus Resp. Streptomyces sp., Catalyzing Side Chain Hydrolysis on the Taxane Core

ChemCatChem, EarlyView.
An enzyme that has been identified and characterized as capable of hydrolyzing paclitaxel (Taxol), a key anticancer drug derived from Pacific yew (Taxus brevifolia) has been identified. Molecular docking (MD) simulations map the catalytic triad and critical residues that drive substrate‐enzyme interactions. The findings indicate the catalytic potential
Jinfen Su, Eugen Schell, Thomas Heine, Marion B. Ansorge‐Schumacher   +3 more
wiley   +1 more source

Methanetetrol and the final frontier in ortho acids. [PDF]

Nat Commun
Marks JH, Bai X, Nikolayev AA, Gong Q, McAnally M, Wang J, Pan Y, Fortenberry RC, Mebel AM, Yang T, Kaiser RI.   +10 more
europepmc   +1 more source

Deciphering Transition Metal Diffusion in Anode Battery Materials: A Study on Nb Diffusion in NbxTi1−xO2

Carbon Energy, EarlyView.
ABSTRACT Demand for fast‐charging lithium‐ion batteries (LIBs) has escalated incredibly in the past few years. A conventional method to improve the performance is to chemically partly substitute the transition metal with another to increase its conductivity.
Ola Kenji Forslund, Carmen Cavallo, Johan Cedervall, Jun Sugiyama, Kazuki Ohishi, Akihiro Koda, Alessandro Latini, Aleksandar Matic, Martin Månsson, Yasmine Sassa   +9 more
wiley   +1 more source

Infrared Spectroscopy of Neutral and Cationic Sumanene (C₂₁H₁₂ & C₂₁H₁₂ ⁺) in the Gas Phase: Implications for Interstellar Aromatic Infrared Bands (AIBs). [PDF]

ACS Earth Space Chem
Sundararajan P, Ferrari P, Brünken S, Buma WJ, Candian A, Tielens A.   +5 more
europepmc   +1 more source

Description of a New Type of Focal Plane Spectroscope and its Application to Astronomical Spectroscopy

, 1902
F. L. O. Wadsworth
openalex   +1 more source

Highly Sensitive, Low‐Cost Deep‐UV Resonant Raman Microspectroscopy Systems

Chemistry–Methods, EarlyView.
Low‐cost deep UV resonant Raman microscope for chemical sensing and imaging has been developed and its performance has been experimentally validated for several potential applications. Multimodal imaging capabilities of a new instrument have been demonstrated as well.
Joseph Harrington, Vsevolod Cheburkanov, Mykyta Kizilov, Ilya Kulagin, Georgi I. Petrov, Vladislav V. Yakovlev   +5 more
wiley   +1 more source

Infrared Spectroscopy of Pentagon-Containing PAHs: Indenyl and Fluorenyl Anions and Indenyl Cation. [PDF]

J Phys Chem Lett
Wenzel G, Jiménez-Redondo M, Ončák M, McGuire BA, Brünken S, Caselli P, Jusko P.   +6 more
europepmc   +1 more source

iSELECTION: An Instrument to Study the Kinetics of Isomer‐Selected Gas‐Phase Ion‐Molecule Reactions

Chemistry–Methods, EarlyView.
Isomer‐specific reactivity is key in cluster chemistry. Herein, it is shown that how combining drift‐tube ion mobility with mass spectrometry enables the derivation of reaction rate coefficients for coexisting C40+$\text{C}_{40}^{+}$ isomers, opening new avenues for studying complex chemical systems ...
Corentin Rossi, Anne P. Rasmussen, Bérenger Gans, Juraj Jašík, Jan Žabka, Marc Albaret, Hugo Bauduin, Christophe Charrière, Jean‐Philippe Dugal, Jérôme Guigand, Catherine Le Bris, Ugo Jacovella   +11 more
wiley   +1 more source