CHIMIA, 2008 Surface-initiated controlled radical polymerization is a powerful strategy to tailor the chemical and physical surface properties of materials.
Laurent Lavanant, Harm-Anton Klok
doaj +1 more source
Catalytic polymeric nanoreactors : more than a solid supported catalyst [PDF]
, 2012 Polymeric nanostructures can be synthesized where the catalytic motif is covalently attached within the core domain and protected from the environment by a polymeric shell.
Bosman, Liu, Wang, Yan
core +2 more sources
Advances in Organocatalyzed Atom Transfer Radical Polymerization
Advances in Polymer Technology, 2019 Atom transfer radical polymerization (ATRP) is one of the most robust tools to prepare well-defined polymers with precise topologies and architectures. Although series of improved ATRP methods have been developed to decrease the metal catalyst loading to
Xin Hu, Ning Zhu, Kai Guo
doaj +1 more source
Synthesis of novel organocatalyzed phenoxazine for free metal atom transfer radical polymerization [PDF]
Polímeros, 2020 In this research, a novel organic photocatalyst of 10-(Perylene-3-yl-10H-Phenoxazine (PHP) has been synthesized successfully from perylene and phenoxazine via Buchwald-Hartwig C-N coupling.
Thu Hoang Vo +7 more
doaj +1 more source
Atom transfer radical polymerization of MMA with a macromolecular ligand in a fluorinated solvent and in supercritical carbon dioxide [PDF]
, 2008 Macromolecular fluorinated ligands were prepared according to a three-step strategy that consists of the random copolymerization of heptadecafluorodecyl acrylate and 2-hydroxyethylacrylate, followed by the esterification of the pendant hydroxyl groups ...
Calberg, Cédric +4 more
core +1 more source
PNIPAM grafted surfaces through ATRP and RAFT polymerization: Chemistry and bioadhesion [PDF]
, 2017 Biomaterials surface design is critical for the control of materials and biological system interactions.Being regulated by a layer of molecular dimensions, bioadhesion could be effectively tailored by polymersurface grafting.
Carrerre, N. +5 more
core +3 more sources
Numerical Simulation of Atom-Transfer Radical Polymerization of tert-butyl Methacrylate [PDF]
Materials Research, 2019 Block copolymers based on tert-butyl methacrylate (tBMA) have many uses, such as thermo‐responsive polymers, amphiphilic copolymers, and many applications in the medical field.
Fiorella Zenaida Fernandez Herrera +1 more
doaj +1 more source
Atom Transfer RaAtom Transfer Radical Polymerization of Methyl Methacrylate Using Bis(2-dodecylsulfanyl-ethyl)-Amine/Copper Bromide: Kinetic Study [PDF]
علوم و تکنولوژی پلیمر, 2018 Hypothesis: In controlled polymerization methods, atom transfer radical polymerization (ATRP) is one of the most successful methods for the polymerization of various monomers with the controlled pattern. Effect of some important parameters on kinetics of
Farnoosh Karimi +2 more
doaj +1 more source
Preparation of Polyacrylamide with Improved Tacticity and Low Molecular Weight Distribution [PDF]
BIO Web of Conferences, 2022 Polyacrylamide with improved tacticity and low molecular weight distribution was obtained via stereospecific atom transfer radical polymerization (ATRP) using the mixture of Lewis acids Y(OTf)3 and AlCl3 in a certain ratio as stereospecific catalyst and ...
Jiang Jianguo +4 more
doaj +1 more source
Controlled atom transfer radical polymerization of MMA onto the surface of high-density functionalized graphene oxide [PDF]
, 2014 We report on the grafting of poly(methyl methacrylate) (PMMA) onto the surface of high-density functionalized graphene oxides (GO) through controlled radical polymerization (CRP). To increase the density of surface grafting, GO was first diazotized (DGO),
Jin Chung, Mukesh Kumar, Seung Hur
core +2 more sources