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Advanced Functional Materials, EarlyView.Inspired by metal‐free carbonic anhydrases (CAs) that achieve efficient catalysis without metal cofactors, we herein report a sequence‐defined supramolecular peptoid platform that mimics metal‐free CAs and exhibits hydrolytic activity via a supramolecular assembly‐mediated proton‐transfer mechanism.
Progyateg Chakma +8 more
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Electrochemistry for Atom Transfer Radical Polymerization
The Chemical Record, 2021 AbstractAtom Transfer Radical Polymerization (ATRP) is the most powerful and most employed technology of Controlled Radical Polymerization (CRP) to produce polymers with well‐defined architecture, that is, composition, topology, and functionality.
Abdirisak Ahmed Isse, Armando Gennaro
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Electrochemically Mediated Atom Transfer Radical Polymerization
Science, 2011 The structure of a polymer can be fine-tuned by rapidly starting and stopping its synthesis.
MAGENAU AJD +3 more
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Atom Transfer Radical Polymerization
Chemical Reviews, 2001Krzysztof Matyjaszewski, Jianhui Xia
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Atom Transfer Radical Polymerization: A Mechanistic Perspective
Journal of the American Chemical Society, 2022Since its inception, atom transfer radical polymerization (ATRP) has seen continuous evolution in terms of the design of the catalyst and reaction conditions; today, it is one of the most useful techniques to prepare well-defined polymers as well as one of the most notable examples of catalysis in polymer chemistry.
Francesca Lorandi +2 more
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Concurrent atom transfer radical polymerization and nitroxide radical coupling relay polymerization
Chemical Communications, 2021Relay polymerization by conjugate radical trapping and re-initiation resulting in polymers with inserted alkoxyamine linkages.
Yu Wang +3 more
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Redox-switchable atom transfer radical polymerization
Chemical Communications, 2019A redox-switchable ATRP was developed in which the copper catalyst, and hence the polymerization, was switched on/off using redox agents.
Sajjad Dadashi-Silab +3 more
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Macromolecular Engineering by Atom Transfer Radical Polymerization
Journal of the American Chemical Society, 2014This Perspective presents recent advances in macromolecular engineering enabled by ATRP. They include the fundamental mechanistic and synthetic features of ATRP with emphasis on various catalytic/initiation systems that use parts-per-million concentrations of Cu catalysts and can be run in environmentally friendly media, e.g., water.
Krzysztof, Matyjaszewski +1 more
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Externally controlled atom transfer radical polymerization
Chemical Society Reviews, 2018ATRP can be externally controlled by electrical current, light, mechanical forces and various chemical reducing agents. The mechanistic aspects and preparation of polymers with complex functional architectures and their applications are critically reviewed.
Xiangcheng Pan +3 more
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Microfluidically mediated atom-transfer radical polymerization
Chemical Communications, 2019Microfluidically mediated atom-transfer radical polymerization can be used to fabricate polymer brushes with a controlled gradient.
Chengtao Zhang +4 more
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