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Polymer catenanes via a supramolecularly templated ATRP initiator
Chemical Communications, 2011Synthesis of polymer catenanes via a living radical polymerization and supramolecular template approach are demonstrated. The ring closure was performed via atom transfer radical cross coupling (ATRC) to obtain polymer catenanes from the linear polymer metal complex precursor.
Ajaykumar, Bunha +2 more
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Mechanism of Halogen Exchange in ATRP
Macromolecules, 2011Detailed mechanistic studies reveal that halogen exchange (HE) in ATRP can occur not only by a radical pathway (atom transfer) but also by an ionic pathway (SN2 reaction) because Cu(I)(L)X and Cu(I...
Chi-How Peng +3 more
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Solid-Phase ATRP Synthesis of Peptide−Polymer Hybrids
Journal of the American Chemical Society, 2004A versatile methodology to prepare hybrid biomaterials by atom transfer radical polymerization from resin-supported peptides has been established. As an example, we have synthesized a GRGDS-functionalized poly(2-hydroxyethyl methacrylate). The peptide-polymer was characterized by solid-state (13)C NMR and GPC and found to have a number average ...
Ying, Mei +4 more
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A comparison of RAFT and ATRP methods for controlled radical polymerization
Nature Reviews Chemistry, 2021Nghia Phuoc Truong +2 more
exaly
Branch-Controlled ATRP Via Sulfoxide Chemistry
Macromolecules, 2021Dongwoo Kim +9 more
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Preparation of biomolecule-polymer conjugates by grafting-from using ATRP, RAFT, or ROMP
Progress in Polymer Science, 2020Marco S Messina, Heather D Maynard
exaly