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High‐valent Rh(IV) and Rh(V) species have been invoked to rationalize enhanced catalytic reactivity. This review examines evidence for both, emphasizing reactions proceeding through the Rh(III)/Rh(IV)/Rh(II) cycle. While Rh(V) intermediates are computationally supported, experimental evidence is limited; Rh(IV) species are supported by both theory and ...
Yujie Cao, Arnav Kacker, Kevin G. M. Kou
wiley +1 more source
Digital welfare‐to‐work in the global south: A case of Indonesian pre‐employment card program
Abstract The worldwide movement toward digitisation in public service delivery presents a range of opportunities and risks. The potential benefits include improved efficiency, more consistent service delivery decisions and enhanced responsiveness to citizens' demand.
Phuc Nguyen+3 more
wiley +1 more source
Robo‐compliance in Australian employment services
Abstract Since the late 1990s, Australia's employment services have enforced mutual obligation compliance as part of a transition to a disciplinary regime of conditional welfare. In recent years, the digitisation of employment services has extended the disciplinary approach to self‐activation.
Simone Casey
wiley +1 more source
Beyond administrative burden: Activation and administrative harm
Abstract Within recent public policy and administration scholarship, there has been a growing focus on the concept of “administrative burden” to describe the learning, compliance and psychological costs incurred by citizens when trying to access services and exercise social and political rights. Specifically, in the context of activation and welfare‐to‐
Michael McGann, Sarah Ball
wiley +1 more source