Results 231 to 240 of about 73,026 (352)

Fused Nitrogen Bridgehead N,O‐Acetals as Versatile Scaffolds: Synthetic Strategies, Mechanism and Applications

open access: yesChemistry – A European Journal, EarlyView.
Fused nitrogen‐bridgehead N,O‐acetals receive specific emphasis as pivotal scaffolds due to their significant role in the bioactivity of medicinally relevant molecules. Significant approaches have been reported on their role as key synthetic building blocks/motifs in the construction of complex organic molecules and their utility as chiral auxiliaries ...
Alexis D. Kouvelas   +2 more
wiley   +1 more source

3,4,5‐Trifluorophenyldiazonium – a unique radical source for the visible light induced, catalyst‐free arylation of tyrosine residues in peptides

open access: yesChemistry – A European Journal, Accepted Article.
The direct radical arylation of tyrosine residues in peptides has been achieved under highly attractive conditions, requiring only the peptide substrate, a 3,4,5‐trifluorophenyldiazonium salt and irradiation with visible light. Being well‐balanced in its reactivity to form strong charge transfer complexes with the phenolic side chain, which are ...
Markus Rolf Heinrich   +5 more
wiley   +1 more source

Ultrasmall Gold Nanoparticles (2 nm) Decorated with a High Density of Photochemically Switchable Ligands

open access: yesChemistry – A European Journal, EarlyView.
Photoswitchable azo ligands can be conjugated to the surface of ultrasmall gold nanoparticles with a high density (about 50 ligands on each nanoparticle). Their photoswitching is not constrained by the binding to the gold surface and can be used to induce a nematic‐to‐isotropic phase transition in a liquid crystal.
Lisa‐Sofie Wagner   +7 more
wiley   +1 more source

THE EFFECT OF SOLVENTS ON THE KINETICS OF CIS-TRANS ISOMERIZATION OF SELECTED AROMATIC AZO COMPOUNDS [PDF]

open access: bronze, 2018
Galyna MIDYANA   +3 more
openalex   +1 more source

Recent Advances in Detergent Chemistry and Handling Support Membrane Protein Analysis Including Lipid Interactions

open access: yesChemistry – A European Journal, EarlyView.
Detergent design parameters determine experimental successes in membrane protein research. Recent progresses in detergent chemistry are reviewed to promote the top‐down design of non‐ionic detergents for the purification and analysis of intact membrane proteins, including lipid interactions.
Katharina Alker   +2 more
wiley   +1 more source

Two-photon induced isomerization through a cyaninic molecular antenna in azo compounds

open access: hybrid, 2021
Emmanuel Villatoro   +7 more
openalex   +2 more sources

Reactions of 1,4‐Diborinine Derivatives with CO2

open access: yesChemPhysChem, EarlyView.
The reaction of CO2 with seven molecules featuring a 1,4‐diborinine central ring is studied by means of density functional theory calculations. The selected systems present five‐ and six‐membered aza rings surrounding 1,4‐diborinine. The computed reactivity trends and origin of regioselectivity are quantitatively analyzed with the activation strain ...
Maxime Ferrer   +3 more
wiley   +1 more source

Spectroscopic Investigations of a Vandalized Contemporary Acrylic Painting on Canvas Using Model Paintings and Chemometrics

open access: yesChemPlusChem, Accepted Article.
The characterization and conservation of materials constituting contemporary art pose a significant challenge for scientists and restorers due to the wide variability and heterogeneity in their compositions and their chemical instability. The aim of this study is to contribute to the understanding of the composition and ageing of materials in ...
Jana Striova   +4 more
wiley   +1 more source

Diazonium Salts in Visible Light Photocatalysis – a Focused Overview of their Application in Continuous Flow Synthesis

open access: yesChemPhotoChem, EarlyView.
The combination of continuous flow technology and visible light photocatalysis has been used to improve the safety and productivity of reactions with diazonium salts as reactive intermediates. This approach has proven to be a reliable method for various organic synthesis routes with diazonium salts under mild and well‐defined conditions.
Christoph Deckers, Thomas H. Rehm
wiley   +1 more source

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