Results 221 to 230 of about 584,132 (297)

Decoupling Thermodynamic and Kinetic Moisture Instability Reveals a Critical Humidity Threshold for Sodium Thiophosphate Solid Electrolyte

open access: yesAdvanced Energy Materials, EarlyView.
A quantitative exposure‐heat treatment framework identifies a critical humidity threshold (15%RH) and heat treatment temperature (80°C) that governs the recoverability of air‐exposed Na3PS4, revealing the decoupled thermodynamic and kinetic contributions to its moisture stability.
Boling Liu   +10 more
wiley   +1 more source

Internal Electric Field‐Guided, Low‐Adsorption Ferroelectric Anode Protective Layers for Sustainable Suppression of Polysulfide Side Reactions in Lithium–Sulfur Batteries

open access: yesAdvanced Energy Materials, EarlyView.
A positively polarized ferroelectric β‐pvdf layer incorporating fluorinated boron nitride nanosheets (PPFBN) establishes a strong internal field that promotes Li+ transport toward the anode while suppressing the migration of polysulfide anions. In addition, its intrinsically low polysulfide affinity helps preserve protective‐layer functionality ...
Daehun Han   +6 more
wiley   +1 more source

Mechanistic Origin of Capacity Limitation in Sidorenkite‐Type Na3‐xFe(PO4)(CO3) Carbonophosphate Cathodes for Na‐Ion Batteries

open access: yesAdvanced Energy Materials, EarlyView.
The potential–capacity profile reveals a one‐electron limitation in sidorenkite Na3−xFe(PO4)(CO3). Structural analysis shows that Fe4+ formation induces lattice strain and suppresses electronic conductivity, blocking further Na extraction. These findings establish key design rules: preserve crystallinity, avoid Jahn–Teller–active d4 configurations, and
Samuel Franz Gatti   +7 more
wiley   +1 more source

“Lithium‐Free” Anode Solid‐State Batteries Enabled by 3D Structured Miec Garnet

open access: yesAdvanced Energy Materials, EarlyView.
“Lithium‐free” anode solid‐state batteries can maximize energy density by eliminating excess lithium metal but are limited by unstable lithium nucleation and poor lithium reversibility at solid interfaces. A mixed ionic and electronic conducting garnet scaffold promotes uniform lithium deposition within a three‐dimensional porous framework at low ...
George V. Alexander   +6 more
wiley   +1 more source

Calendering‐Dependent Electrochemical and Cost‐Energy Tradeoffs in Layered – Olivine Blend Cathodes

open access: yesAdvanced Energy Materials, EarlyView.
Blends comprised of LiNi0.9Mn0.05Co0.05O2 (NMC) and LiMn0.7Fe0.3PO4 (LMFP) are investigated to assess the performance – cost tradeoffs. Their rate‐capability benefit is retained only under uncalendered‐to‐moderately calendered states. Although blends reduce voltage decay and improve energy retention, they do not deliver measureable improvement in ...
Huyen T. K. Nguyen, Arumugam Manthiram
wiley   +1 more source

Joule self‐heating enabled oxygen transport and coupled methane reactions in a La0.6Sr0.4Co0.2Fe0.8O3‐δ hollow fiber membrane reactor

open access: yesAIChE Journal, EarlyView.
Abstract Mixed‐conducting ceramic hollow fiber membranes are a versatile platform for oxygen separation, value‐added chemical production, and oxy‐combustion. Because oxygen permeation is thermally activated, these systems typically rely on bulky, energy‐intensive furnaces that suffer from low efficiency and large thermal inertia.
Gang Wang   +2 more
wiley   +1 more source

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