Angewandte Chemie, EarlyView.A mechano‐triggered polythiourethane (PTU) synthesis mediated by a two‐electron pathway. The polymerization proceeds efficiently (<1 h) under focused ultrasound, achieving >90% conversion without any conventional base catalyst. The approach demonstrates broad compatibility with various thiol/isocyanate monomer combinations, highlighting its synthetic ...
Yixiao Dong +7 more
wiley +2 more sources
Effect of Ball Mill Treatment on the Physicochemical Properties and Digestibility of Protein Extracts Generated from Scallops (Chlamys farreri). [PDF]
Int J Mol Sci, 2018 Wu D, Wu C, Chen H, Wang Z, Yu C, Du M.
europepmc +1 more source
Mechanophotochemistry: Lighting up EDA Complexes in the Solid State
Angewandte Chemie, EarlyView.Examples of mechanophotochemical EDA complex‐mediated radical reactions, including a Giese reaction, a C─S cross‐coupling reaction, a phosphorylation reaction, and a sulfonylation reaction are shown to rapidly proceed in air using visible light excitation.
Aniket Kumar Srivastawa +1 more
wiley +2 more sources
Radical, Not Ionic: The Mechanochemical Zincke Nitration of Phenols
Angewandte Chemie, EarlyView.Mechanochemistry recasts the classical Zincke nitration as an open‐shell process. Liquid‐assisted vibrational milling of phenols with in situ HNO2 delivers direct and ipso nitration across 50 substrates, while atmosphere, NOx‐transfer, EPR and DFT evidence expose a phenoxyl‐radical/NO2 manifold underlying this historically ionic transformation ...
Roberto Scipione +7 more
wiley +1 more source
Redox‐Modulated σ‐Bond Reactivity in a Radical‐Anion Dimer
Angewandte Chemie International Edition, Volume 65, Issue 44, 26 October 2026.A radialene‐based radical anion σ‐dimer comprising an elongated C‐C bond exhibits orthogonal stimuli responsiveness. Homolytic cleavage of the dimer to the radical state is triggered by mechanical strain and high temperature. Dimer scission is also achieved via oxidation, resulting in formation of neutral radialenes.
Sushil Ranjan Bhatta +8 more
wiley +1 more source
Mechanochemical synthesis using hypervalent iodine reagents. [PDF]
Beilstein J Org ChemAmri N.
europepmc +1 more source
Enhanced Dispersion and Structural Homogeneity in LDPE/Bi<sub>2</sub>O<sub>3</sub>/B<sub>4</sub>C Composites via Cryogenic Ball Milling with Binary-Sized Grinding Media. [PDF]
Materials (Basel)Pavlenko VI +4 more
europepmc +1 more source
Grinding Ball Wear and Equilibrium Ball Load in a Ball Mill
Journal of the Mining Institute of Japan, 1974 openaire +2 more sources
Overview of Research Progress and Development of Cathode Materials for Aqueous Na‐Ion Batteries
Asia-Pacific Journal of Chemical Engineering, EarlyView.ABSTRACT Aqueous sodium‐ion batteries (ASIBs) have now been viewed as the promising energy storage technique for the grid application due to their intrinsic safety and cost‐effectiveness. However, their energy density and cycling stability are still unsatisfactory accompanied by the narrow electrochemical stability window of water and parasitic side ...
Zhiwei Shi +5 more
wiley +1 more source
Glyoxylic‐Acetal‐Based Gel‐Polymer Electrolytes for Lithium‐Ion Batteries
Batteries &Supercaps, Volume 8, Issue 3, March 2025.A safe electrolyte based on tetraethoxyglyoxal (LE) is combined with a methacrylate polymer matrix. The resulting gel‐polymer electrolyte (GPE) exhibits an increased flash point, suitable ionic conductivity, and a stable performance in lithium‐ion battery cells.
Christian Leibing +4 more
wiley +1 more source