Results 191 to 200 of about 19,800 (263)

Maximizing Active Site Density in Tin Single‐Site Catalysts for Selective Carbon Dioxide to Formate Electroreduction

open access: yesAngewandte Chemie, EarlyView.
High‐loading tin single‐site catalysts (>7.5 wt.% Sn) are synthesized using a nitrogen‐enriched carbon scaffold and mechanochemically assisted pyrolysis to stabilize atomically dispersed Sn. The resulting Sn/N‐C‐M catalyst enables highly selective CO2‐to‐formate conversion (>90% FE across 50–500 mA cm−2) with long‐term durability and operando‐verified ...
Katharina Potemkin   +12 more
wiley   +1 more source

Unlocking Zn‐Ion Diffusion in Disordered Rocksalt Cathodes for Nonaqueous Zn‐Ion Batteries

open access: yesAngewandte Chemie, EarlyView.
Developing viable cathode materials for multivalent battery chemistries is challenging due to the intrinsic sluggish diffusion kinetics. A disordered rocksalt oxide host was found to “lock” the cycling of zinc ions from nonaqueous electrolyte. We unlock zinc ion diffusion in the disordered rocksalt by introduction of a percolating vacancy network ...
Zixuan Li   +10 more
wiley   +1 more source

Borylcyclopropanes: Synthetic Strategies and Applications

open access: yesAngewandte Chemie, EarlyView.
Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley   +1 more source

Magnesium‐Retention Assisted Synthesis of High‐Performance Zintl Thermoelectrics

open access: yesAngewandte Chemie, EarlyView.
Mg volatilization and chemical instability during high‐temperature synthesis hinder the scalable fabrication of Mg‐based thermoelectrics. Here, a magnesium‐retention assisted synthesis (MRAS) strategy stabilizes Mg using a sacrificial Mg reservoir and an inert‐gas‐regulated melting environment.
Boxuan Hu   +9 more
wiley   +1 more source

Mechanochemical Dehydrogenative Phenochalcogenazination: A Pronounced Water Effect. [PDF]

open access: yesChemSusChem
Paffen A   +5 more
europepmc   +1 more source

Safe and Sustainable by Design (SSbD) Synthesis of Food and Personal Care Ingredients by Mechanochemistry. [PDF]

open access: yesChemSusChem
Solórzano-Rodríguez R   +7 more
europepmc   +1 more source

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