Iron Catalyzed Aryl–Aryl Kumada Cross‐Coupling: A Mechanistic and Computational Investigation
Despite intense interest, the mechanism of iron‐catalyzed aryl–aryl cross‐coupling remains poorly understood. Combining Mössbauer spectroscopy, kinetics analysis, and DFT computations these studies reveal a novel Fe(I)/Fe(II)/Fe(III) catalytic for aryl–aryl cross‐coupling mediated by an Fe(II) PCNHCP Pincer complex. These findings close a key knowledge
Jatin Panda +11 more
wiley +2 more sources
Three-Dimensionally Printed Microstructured Hydrophobic Surfaces: Morphology and Wettability. [PDF]
Tammaro L +9 more
europepmc +1 more source
Facilitating Genetic Testing for Perinatal Demise: Development of a Multidisciplinary Workflow
ABSTRACT Genetic contributors to perinatal demise are common but frequently undiagnosed due to clinical and logistical barriers. We aimed to improve access to genetic for intrauterine fetal demise (IUFD), stillbirth, and early neonatal death by developing a multidisciplinary workflow.
Mackenzie Mosera +15 more
wiley +1 more source
Bifaciality Optimization of TBC Silicon Solar Cells Based on Quokka3 Simulation. [PDF]
Yang F +8 more
europepmc +1 more source
ABSTRACT The ciliopathies are a group of genetic disorders caused by defective function of either the primary cilia (a large number) or the motile cilia (a much smaller number). These have been defined as diseases with mutations in genes encoding individual ciliary or cilia‐associated proteins.
Robert P. Erickson +1 more
wiley +1 more source
Precision detection of micro-damage on conveyor belt surfaces using laser scanning and deep learning techniques. [PDF]
Li Y +5 more
europepmc +1 more source
Thermally Distinguishable Polyhedral Shapes in Chemistry: 6- and 7‑Coordination. [PDF]
Munguba GHL +4 more
europepmc +1 more source
Copper binding triggers structural changes that expose a reactive disulphide bridge, enabling intrinsic Cu(II) reduction in folded proteins. SAXS, XAS, and QM/MM simulations reveal how globular proteins such as HSA and SOD1 employ disulphide‐mediated dynamics to modulate site accessibility and control copper redox chemistry.
Rebecca Sternke‐Hoffmann +9 more
wiley +1 more source
Postnatal interaction of size and shape in the human endocranium and brain structures. [PDF]
Takagi K, Kondo O.
europepmc +1 more source
From Bench to Bulk: Investigating Kinetics, Recyclability, and Scale‐Up of ZIF‐67
ABSTRACT Zeolitic imidazolate framework‐67 (ZIF‐67), a subclass of metal–organic frameworks (MOFs), has garnered considerable attention due to its high surface area, open crystal structure, tunable porosity, and potential applications in gas separation, catalysis, and carbon capture.
Aaush Bhardwaj Singh +1 more
wiley +1 more source

