Results 101 to 110 of about 485,699 (306)

Nanocrystalline TiO2 and halloysite clay mineral composite films prepared by sol-gel method:Synergistic effect and the case of silver modification to the photocatalytic degradation of basic blue- 41 azo dye in water [PDF]

open access: yes, 2014
Tubular halloysite clay mineral and nanocrystalline TiO2 were incorporated in the preparation of nanocomposite films on glass substrates via sol-gel method at 450 °C.
Kaplani, E.   +4 more
core  

Role of Histidine‐Containing Peptoids in Accelerating the Kinetics of Calcite Growth

open access: yesAdvanced Functional Materials, EarlyView.
Amphiphilic histidine‐containing peptoids mimic carbonic anhydrase (CA) to accelerate calcite step growth. In the presence of Zn2+, they promote the deprotonation of HCO3−, the desolvation of Ca2+, and the reorganization of interfacial hydration layers, thereby reducing the activation barrier for calcite growth.
Mingyi Zhang   +5 more
wiley   +1 more source

Preyssler Heteropolyacids in the Self-Etherification of 5-Hydroxymethylfurfural to 5,5′-[Oxybis(methylene)]bis-2-furfural Under Mild Reaction Conditions [PDF]

open access: yes, 2017
The synthesis of 5,5′-[oxybis(methylene)]bis-2-furfural (OBMF) from 5-hydroxymethylfurfural (5-HMF) was studied using bulk and alumina-supported Preyssler heteropolyacids (HPAs). The formation of OBMF was related to the amount of Brønsted acid sites, and
Afonso, Carlos A. M.   +6 more
core   +1 more source

Block Copolymers: Emerging Building Blocks for Additive Manufacturing

open access: yesAdvanced Functional Materials, EarlyView.
This review addresses how block copolymer (BCP) physics and rheology have led to the widespread use of BCPs in advanced additive manufacturing techniques, with particular emphasis on the untapped potential of these nanostructured materials toward achieving multi‐scale architected materials with unique, programmable material properties.
Alice S. Fergerson   +3 more
wiley   +1 more source

Organocatalytic stereodivergent synthesis of β,β-disubstituted-α-aminoacids [PDF]

open access: yes, 2017
In this work, we present an organocatalytic stereodivergent synthesis of β,β-disubstituted-α-aminoacids using arylidene azlactones as starting materials.
Martinelli, Ada
core  

Self‐Refreshing Bi‐Based Active Sites for Efficient and Durable Electrochemical CO2 Reduction

open access: yesAdvanced Functional Materials, EarlyView.
A self‐refreshing Bi‐based catalyst is developed through the fabrication of a novel basic bismuth nitrate pre‐catalyst, which exhibits differential active sites of Bi2O2CO3 at low potentials and metallic Bi phases at high potentials, self‐repairing capability, and thus wide‐potential‐window efficiency and ultralong durability toward electrochemical CO2
Yuxuan Xiao   +7 more
wiley   +1 more source

OTIMIZAÇÃO DO PROCESSO DE TRANSESTERIFICAÇÃO EM DUAS ETAPAS PARA PRODUÇÃO DE BIODIESEL ATRAVÉS DO PLANEJAMENTO EXPERIMENTAL DOEHLERT

open access: yesQuímica Nova, 2016
In this work, Doehlert experimental design was used to optimize the Transesterification Double Step Process (TDSP) method of methyl soybean oil biodiesel production which starts with a basic catalysis followed by an acidic catalysis.
Carla F. C. Ruschel   +3 more
doaj   +1 more source

Macrocyclic cyanocobalamin (vitamin B12) as a homogeneous electrocatalyst for water oxidation under neutral conditions

open access: yes, 2020
Highly water-soluble cyanocobalamin (also known as vitamin B-12) is the most structurally macrocyclic complex comprising cobalt in the center of a corrin ring.
Ahmad, Nazir   +5 more
core   +1 more source

Proteins, Processing, and Properties of Adhesive Fluid Condensates Purified from Mussels

open access: yesAdvanced Functional Materials, EarlyView.
Mussels exhibit an unmatched proficiency for adhering to wet surfaces in salty environments—a remarkable ability that could inspire new biomedical and technical glues. The fluid protein condensates used to form the underwater mussel glue are extracted, reconstituted and characterized with advanced spectroscopy and nanomechanical analysis, revealing ...
Mathieu D. Rivard   +8 more
wiley   +1 more source

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