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Basic properties of molybdenum and tungsten nitride catalysts
Applied Catalysis A: General, 2005Abstract The basic and related properties of high surface area Mo2N and W2N catalysts were characterized using CO2-temperature programmed desorption (TPD), the decomposition and dehydration of 2-methyl-3-butyn-2-ol (MBOH), and changes in the reaction rates on the addition of CO2, a base site poison.
Randolph C.V. McGee +2 more
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ChemCatChem, 2017
AbstractThe aqueous‐phase hydrogenolysis of xylitol into glycols over Ru/C was performed in the presence and absence of a wide range of concentrations of Ca(OH)2 to investigate the reaction pathway. Without base, epimerization and cascade decarbonylation were the predominant reactions with high selectivities to C5 and C4 alditols and light alkanes at ...
Maxime, Riviere +5 more
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AbstractThe aqueous‐phase hydrogenolysis of xylitol into glycols over Ru/C was performed in the presence and absence of a wide range of concentrations of Ca(OH)2 to investigate the reaction pathway. Without base, epimerization and cascade decarbonylation were the predominant reactions with high selectivities to C5 and C4 alditols and light alkanes at ...
Maxime, Riviere +5 more
openaire +2 more sources
Relationships between basicity and reactivity of zeolite catalysts
Research on Chemical Intermediates, 2000A wide variety of characterization methods, including UV-vis spectroscopy of adsorbed I2, microcalorimetry of CO2 adsorption, and x-ray absorption spectroscopy at the Cs LIII edge of zeolite cations, was applied to a series of alkali containing zeolites in order to elucidate the nature of the basic sites on these materials. In addition, three catalytic
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Role of oxide catalysts basicity in selective oxidation
1992Abstract Rates of oxidative coupling and ammoxidation of some hydrocarbons are found to increase linearly with increasing the amounts of weak and moderate basic sites on a surface of oxide catalyst. Such a correlation indicates that hydrocarbon activation occurs via the C-H bond heterolytic dissociation under the attack of catalyst basic site ...
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Journal of Catalysis, 1969
CO2 adsorption has been measured on seven silica catalysts containing different amounts of sodium. The results are compared with those of a previous study of ammonia adsorption. As with NH3, the adsorption of CO2 increases with sodium content, but evidence is presented to show that the centers for adsorption of CO2 and NH3 are different. The adsorption
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CO2 adsorption has been measured on seven silica catalysts containing different amounts of sodium. The results are compared with those of a previous study of ammonia adsorption. As with NH3, the adsorption of CO2 increases with sodium content, but evidence is presented to show that the centers for adsorption of CO2 and NH3 are different. The adsorption
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Microkinetic Modeling: A Tool for Rational Catalyst Design
Chemical Reviews, 2021Ali Hussain Motagamwala, James A Dumesic
exaly
MOF-enabled confinement and related effects for chemical catalyst presentation and utilization
Chemical Society Reviews, 2022Jian Liu +2 more
exaly

