Results 171 to 180 of about 3,308,792 (258)

31P Solid‐State NMR‐Enabled Development of a Pt/Aluminum Tripolyphosphate Catalyst for Selective C─O Bond Hydrogenolysis of Phenols

Angewandte Chemie, EarlyView.
31P solid‐state nuclear magnetic resonance analysis revealed the presence of aluminum tripolyphosphate on the surface of a platinum/aluminum condensed phosphate mixture (ACPM) catalyst. This finding led to the development of a Pt/aluminum tripolyphosphate (Pt/ATPP) catalyst for the selective hydrogenolysis of phenols to arenes.
Kento Oshida, Akito Ai, Shinji Tanaka, Yuichiro Okuzumi, Yuga Ezoe, Takeyuki Nogami, Rin Seki, Hiroki Miura, Tetsuya Shishido, Akira Nakayama, Xiongjie Jin, Kyoko Nozaki   +11 more
wiley   +2 more sources

An Autonomous Large Language Model‐Agent Framework for Transparent and Local Time Series Forecasting

Advanced Intelligent Discovery, EarlyView.
Architecture of the proposed large language model (LLM)‐based agent framework for autonomous time series forecasting in thermal power generation systems. The framework operates through a vertical pipeline initiated by natural language queries from users, which are processed by the LLM Agent Core powered by Llama.cpp and a ReAct loop with persistent ...
William Gouvêa Buratto, Gabriel Villarrubia Gonzalez, Ademir Nied, Laio Oriel Seman, Anne Carolina Rodrigues Klaar, Stefano Frizzo Stefenon   +5 more
wiley   +1 more source

Acetylene Semi‐Hydrogenation by Photocatalysis

Angewandte Chemie, EarlyView.
Photocatalytic acetylene semi‐hydrogenation is an emerging light‐driven route to polymer‐grade ethylene, offering a mild alternative to energy‐intensive thermocatalysis. By replacing H2 co‐feed with water or other proton sources, these systems can achieve high selectivity under ambient conditions.
Anna Fortunato, Brando Adranno, Sharon Silloni, Marianna Barbieri, Claudia Masia, Francesca Arcudi, Luka Đorđević   +6 more
wiley   +2 more sources

Explainable machine learning to predict root biomass of field crops using UAV multispectral data. [PDF]

Front Plant Sci
Shan R, Wang G, Jia S, Liang X, Li F, Zhang W.   +5 more
europepmc   +1 more source

The causal effect of agricultural landscape simplification on Germany's grasslands during a compound drought and heatwave in 2018

American Journal of Agricultural Economics, EarlyView.
Abstract Preserving ecosystem services, along with economic and environmental benefits, will require future landscape policies to identify and incorporate relevant landscape features. In this paper, we investigate the causal effect of agricultural landscape simplification on drought‐related grassland damages.
Marco Ferro, Jan Börner, Silke Hüttel, Katja Kowalski, Patrick Hostert, Krisztina Kis‐Katos   +5 more
wiley   +1 more source

High‐Tg Polythioesters From Isomerization Ring‐Opening Polymerization of a Renewable Oxanorbornane‐Fused Thionolactone

Angewandte Chemie, EarlyView.
A biobased tricyclic thionolactone undergoes selective isomerization ring‐opening polymerization to yield a high‐molecular‐weight polythioester with an exceptionally high Tg of 171°C, exceeding that of the analogous polyester. The polythioester efficiently depolymerizes through backbiting, while its hydrolysis and methanolysis reveal the critical ...
Eva Harsevoort, Henk‐Jan Akkerman, Martin Lutz, Arnaud Thevenon, Pieter C. A. Bruijnincx   +4 more
wiley   +2 more sources

Sweet Woodruff (<i>Galium odoratum</i> L.)-More than Just Coumarin: From Fundamental to Biomass Valorization. [PDF]

Molecules
Herre I, Stegemann T.
europepmc   +1 more source

Success of coastal sage scrub restoration is influenced by local adaptations of shrub species

American Journal of Botany, EarlyView.
Abstract Premise Restoring plant communities is increasingly challenging with climate change. While practitioners have traditionally used local seed sources, many are recommending assisted migration, possibly from more extreme environments such as inland rather than coastal environments, for restoration.
Moises R. Perea‐Vega, Megan E. Lulow, Julie E. Coffey, Amy K. Henry, Katharina T. Schmidt, Priscilla M. Ta, Kailen A. Mooney, Sarah Kimball   +7 more
wiley   +1 more source

Sustainable Access to N‐Heterocycles: One‐Pot Cascade Synthesis of Pyrroles From Bio‐Derived Furans

Angewandte Chemie, EarlyView.
Highly dispersed platinum (Pt) clusters on Brønsted acid‐rich HY zeolite enable a one‐pot cascade conversion of bio‐derived furans and nitroarenes into pyrroles. Highly dispersed Pt sites ensure selective nitro hydrogenation, while Pt nanoparticles promote undesired over‐hydrogenation.
Haifeng Qi, Germán López Robledo, Jianglin Duan, Yujing Ren, Kathrin Junge, Matthias Beller   +5 more
wiley   +2 more sources

Nanostructured Deep Eutectic Systems in Healthcare: From Bioactive Solvents to Intelligent Biointerfaces, Wearables, and AI‐Driven Design

Advanced NanoBiomed Research, EarlyView.
Beyond the green solvent paradigm, this review redefines Deep Eutectic Systems (DES) as programmable supramolecular nanoassemblies. We survey their biomedical convergence: stabilizing thermolabile mRNA to enable cold chain‐free logistics, reshaping transdermal microneedle delivery, enabling long‐term wearables via eutectogels, and utilizing Generative ...
Jeesu Moon, Min Seo Kim, Jae‐Seung Lee
wiley   +1 more source