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Bimetallic Catalytic Synthesis of Anellated Benzazepines.

ChemInform, 2005
AbstractFor Abstract see ChemInform Abstract in Full Text.
Laura A T, Cleghorn   +4 more
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2‐benzazepines. 10 [1]. New d‐fused 2‐benzazepines

Journal of Heterocyclic Chemistry, 1989
AbstractPyrano[3,2‐d][2]benzazepines were synthesized by reaction of the beta‐dimethylamino unsaturated ketone 1 with malonic ester or the anion of t‐butyl acetate. Conversion of the pyrano derivative to the pyrido[3,2‐d]‐[2]benzazepine was achieved in low yield.
Armin Walser, Louis Todaro
openaire   +1 more source

ChemInform Abstract: 2‐Benzazepines. Part 10. New d‐Fused 2‐Benzazepines.

ChemInform, 1990
AbstractThe preparations of further pyrano(3,2‐d)(2)benzazepines and related compounds are described.
A. WALSER, L. TODARO
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2‐Benzazepines. 7. Synthesis of pyrimido[5,4‐d][2]benzazepines

Journal of Heterocyclic Chemistry, 1983
AbstractTwo novel syntheses of pyrimido[5,4‐d][2]benzazepines are described. The first synthesis started with 3‐phenylphthalide which in three steps was converted to a functionalized pyrimidine which was cyclized to give the 2‐benzazepine ring system.
James V. Earley   +2 more
openaire   +1 more source

Fused [1]Benzazepines. Pentacyclic [1]Benzazepines by Reaction of 1H-[1]Benzazepine-2,5(3H,4H)-dione with Aldehydes

HETEROCYCLES, 1995
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
openaire   +2 more sources

ChemInform Abstract: 2‐Benzazepines. Part 9. Synthesis and Chemistry of 3H‐2‐Benzazepine and Pyrimido(4,5‐d)(2)benzazepine Derivatives.

ChemInform, 1987
AbstractThe benzazepines (II), prepared from the acetylenes (I), are transformed into the isomeric esters (VI) and (VII) by consecutive bromination, dehydrobromination, and palladium‐catalyzed alkoxycarbonylation.
E. J. TRYBULSKI   +4 more
openaire   +1 more source

Electrochemical oxidation of 2,5-dihydro-1h-1-benzazepines : Synthesis of 5H-1-benzazepines

Tetrahedron, 1995
Abstract Formation of 5H-1-benzazepines was observed after electrochemical oxidation of the title compounds in a flow cell at a graphite felt anode and in acetic buffer. In basic medium, coupling reaction also occurs leading to [2,5-dihydro-1H-1-benzazepin-1-yl]-5H-1-benzazepines. Oxidation mechanisms are discussed.
B. Kharraz   +5 more
openaire   +1 more source

Preparation d'hexahydroisoquinoleino [3,2-b] benzazepines-3; transposition en hexahydroisoquinoleino [2,1-b] benzazepines-2

Tetrahedron, 1983
Abstract Pictet-Spengler cyclisation of threo 1-hydroxy-2-(3',4'-methylenedioxybenzyl)-7, 8-dimethoxy-2,3,4,5-tetrahydro-1H 3-benzazepine 2b gives a mixture of diastereoisomers of 14-hydroxy-2,3-dimethoxy-10,11-methylenedioxy-5,6,8,13,13a,14-hexahydroisoquino [3,2-b] 3-benzazepine 3a and 3b .
A. Graftieaux, J. Likforman, J. Gardent
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ChemInform Abstract: 2‐BENZAZEPINES. 7. SYNTHESIS OF PYRIMIDO(5,4‐D)(2)BENZAZEPINES

Chemischer Informationsdienst, 1984
AbstractDas 3‐Phenyl‐phthalid (I) wird mit dem Anion des Acetonitrils zu Hydroxyisobenzofuran (II) umgesetzt.
J. V. EARLEY, R. I. FRYER, N. W. GILMAN
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Regioselective alkylation reactions of 2,4-diphenyl-3H-1-benzazepine give either 3-alkyl-3H-1-benzazepines or 1-alkyl-1H-1-benzazepines

Tetrahedron Letters, 2014
2,4-Diphenyl-3H-1-benzazepine is deprotonated with either LDA or KHMDS. The resulting anion is alkylated with alkyl halides or MeOTs, giving either products of alkylation at C3, or at N, or a mixture of both. The regioselectivity depends on the base, presence of the complexing agent HMPA, and the leaving group of the alkylating agent.
Allen Ko   +7 more
openaire   +1 more source

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