Results 141 to 150 of about 128,406 (294)

Monosubstituted N‐Arylhydroxylamine Chemistry: Integrating Contemporary Synthetic Approaches for the Efficient Construction of Diverse Heterocyclic Scaffolds

open access: yesChemistry – A European Journal, EarlyView.
Monosubstituted N‐arylhydroxylamines represent a unique subclass of hydroxylamines that act as pivotal intermediates in redox transformations and as versatile platforms for further synthetic transformations. They serve as key building blocks in the synthesis of architecturally complex heterocycles and other valuable organic compounds.
Michael G. Kallitsakis   +2 more
wiley   +1 more source

Self‐Complementary Dimers Based on Zwitterionic Halogen Bond Donors

open access: yesChemistry – A European Journal, EarlyView.
In this study we present the first isolated zwitterionic homodimers based on halogen bonding (XB). After optimization of the structures by changing the Lewis base (LB) and the backbone, their dimerization was observed in gas phase, as well as, in solid state.
Dana Kutzinski   +5 more
wiley   +1 more source

Steric Effects of Alkyl Ammonium Salts on the Combustion of Exchanged Smectite Clays [PDF]

open access: yes, 2018
Bomb calorimetry was explored as a new method for determining the cation exchange capacity (CEC) of clays. Smectite clays were modified with several alkyl ammonium salts varying in number of carbons and the spatial orientation of the carbons about the ...
Keith, Celeste A.
core   +1 more source

Harnessing Random Polymers as Chemoselective Catalysts With Structural Adaptability: Epoxidation of Olefinic Quaternary Ammonium Salts via Charge Recognition

open access: yesChemistry – A European Journal, EarlyView.
The development of chemoselective catalysts that operate across structurally diverse substrates remains a long‐standing challenge. Here, we demonstrate that a random heteropolymer bearing carboxylic acid and urea residues functions as a general epoxidation catalyst for olefinic quaternary ammonium salts.
Yusei Fujii   +2 more
wiley   +1 more source

In‐situ asphaltene capture with iron oxide nanoparticles in steam‐assisted gravity drainage (SAGD) for improved recovery and partial upgrading of bitumen

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Key improvements obtained by incorporating nanoparticles into a lab‐scale SAGD process configuration. The bar plots show enhanced oil recovery, reduced viscosity, and increased asphaltene adsorption in nanoparticle‐assisted scenarios compared with conventional SAGD.
Luis Prada   +6 more
wiley   +1 more source

Polysilane‐Supported Nickel as an Efficient Catalyst for the Hydrogenation of Aromatic Compounds†

open access: yesChinese Journal of Chemistry, EarlyView.
A Ni/Si catalyst obtained from the reaction of poly(monohydro)silane with Ni(cod)2 serves as an effective heterogeneous catalyst for the hydrogenation of arenes under reaction conditions that are significantly milder than those required for conventional nickel‐based catalysts such as Raney nickel.
Hiromu Baba, Yusuke Sunada
wiley   +1 more source

Naphthenic acids removal using N-doped hemp fibers based mesoporous carbon from aqueous waste stream

open access: yesEnergy Nexus
There is a substantial need for removing the contaminants from aqueous waste stream using affordable, stable, and active adsorbents, such as heteroatom-doped carbonaceous materials.
Manju Gurung   +4 more
doaj   +1 more source

Selective Modification of the Product Profile of Biocatalytic Hydrolyzed PET via Product‐Specific Medium Engineering

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
The product profile of enzymatically hydrolyzed PET can be modified by medium engineering and thereby adapted to a desired product. TPA, MHET or BHET can be forced as the predominant product using a basic pH (blue), 25 % ethylene glycol (EG) and IsPETasewt (green) or ≥25 % EG and LCCICCG (pink), respectively.
Tobias Heinks   +8 more
wiley   +1 more source

Photoreversible Polyurea Actuators With Spatiotemporal Control and Adaptive Mechanics

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A light–thermal responsive polyurea network incorporating reversibly dimerizable anthracene units enables spatiotemporal modulation of cross‐linking density and nearly 400‐fold stiffness tuning. Integrating programmable anisotropy, photopatterning, self‐healing, and photowelding within a single framework, this bioinspired “one network–multifunction ...
Zhiwen Song   +7 more
wiley   +1 more source

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