Results 11 to 20 of about 26,979 (280)

A New Synthesis of p-Hydroxy Phenylglycine and Some Analogues from p-Benzoquinone

open access: yes, 2016
A new route to p-hydroxy phenylglycine and N-substituted analogues has been developed starting from p-benzoquinone. 1,2-Addition of methyl lithioacetate to p-benzoquinone and subsequent quenching of the oxygen anion with methyl chloroformate, followed by
Gerardus T. M. Titulaer (3076158)   +3 more
core   +16 more sources

The ground state fundamentals of p-benzoquinone and p-benzoquinone-d4 [PDF]

open access: yesJournal of Molecular Spectroscopy, 1974
Abstract The solid state infrared and Raman spectra of p -benzoquinone and several isotopic derivatives are reported and compared with the results of previous solution and vapor phase studies and with the results of previously published normal coordinate analyses.
Dunn, Thomas M., Francis, Anthony H.
openaire   +3 more sources

Spin-Carrying Benzoquinone Derivatives

open access: yes, 2016
Several 1,4-benzoquinone derivatives carrying oxy-TEMPO radical(s) at the 2-position or 2,5-positions were found to give black crystals by recrystallization from pale yellow solutions and it was revealed from their crystal structures that unusual single ...
Hideto Suzuki (2330695)   +4 more
core   +9 more sources

Antimicrobial Abietane-Type Diterpenoids from Plectranthus punctatus

open access: yesMolecules, 2017
Four new para-benzoquinone containing abietane-type diterpenoids (1–4) along with thirteen known diterpenoids (5–17) were isolated from the roots of Plectranthus punctatus.
Negera Abdissa   +2 more
doaj   +1 more source

A visible-light-induced, metal-free bis-arylation of 2,5-dichlorobenzoquinone

open access: yesBeilstein Journal of Organic Chemistry, 2021
A metal-free protocol for the direct bis-arylation of 2,5-dichlorobenzoquinone with aryldiazonium salts is reported. The reactive salts are generated in situ and converted to radicals through irradiation with visible light.
Pieterjan Winant, Wim Dehaen
doaj   +1 more source

Aqueous Ti(IV)-Catalyzed Diels-Alder Reaction

open access: yesMolecules, 2007
The aqueous Diels-Alder reaction of 1,3-cyclohexadiene with 1,4-benzoquinone was compared and contrasted to the same reaction catalyzed with Flextyl P™, a novel Ti(IV) performance catalyst.
Kyle E. Litz
doaj   +1 more source

Design, synthesis and α-glucosidase inhibition study of novel embelin derivatives

open access: yesJournal of Enzyme Inhibition and Medicinal Chemistry, 2020
Embelin is a naturally occurring para-benzoquinone isolated from Embelia ribes (Burm. f.) of the Myrsinaceae family. It was first discovered to have potent inhibitory activity (IC50 = 4.2 μM) against α-glucosidase in this study.
Xiaole Chen   +11 more
doaj   +1 more source

4'-Bromophenyl Triptycene-2,5-diol

open access: yesMolbank, 2013
Diels Alder reaction of 4-bromophenylquinone (Br-PQ) with anthracene, followed by reduction affords the desired 4'-bromophenyl triptycene-2,5-diol (T-Br-PH).
Mahadevappa Y. Karidurganavar   +2 more
doaj   +1 more source

Copper and Cobalt Co‐catalyzed Selective Electrooxidation of Phenol to p‐Benzoquinone Under Mild Conditions

open access: yesChemElectroChem, 2023
Selective oxidation is still a challenge for targeted conversion of biomass derived substance to high‐value added products. Herein we report an efficient electrochemical strategy to transform phenol into p‐benzoquinone, by tandem oxidations of CuSO4 and ...
Weizhuo Xu   +4 more
doaj   +1 more source

Oxidative cycloaddition of hydroxamic acids with dienes or guaiacols mediated by iodine(III) reagents

open access: yesBeilstein Journal of Organic Chemistry, 2018
[Bis(trifluoroacetoxy)iodo]benzene (BTI) and (diacetoxyiodo)benzene (DIB) efficiently promote the formation of acylnitroso species from hydroxamic acids in the presence of various dienes to give the corresponding hetero-Diels–Alder (HDA) adducts in ...
Hisato Shimizu   +5 more
doaj   +1 more source

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